表单
liquid
质量水平
浓度
1.7 M (in PAO/hexanes mixture)
颜色
colorless to yellow
储存温度
2-8°C
SMILES字符串
[Li]C(C)(C)C
InChI
1S/C4H9.Li/c1-4(2)3;/h1-3H3;
InChI key
BKDLGMUIXWPYGD-UHFFFAOYSA-N
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一般描述
tert-Butyllithium solution (tert-BuLi) is an organolithium compound, used as a strong base in organic chemistry. It facilitates lithium-halogen exchange reaction and also can be employed in the deprotonation of C-H compounds and amines. This tert-BuLi is a solution in poly-α-olefin (PAO)/hexanes solvent mixture is considered non-pyrophoric which is demonstrated using EPA’s SW-846 Test Method 1050.
应用
tert-Butyllithium solution can be used as a strong base in the synthesis of: Alkyllithium derivatives form alkyl iodides and diiodoalkanes by halogen-lithium exchange reaction. Inorganic polymer [(LiMo3Se3)n] from [(InMo3Se3)n] by reductive intercalation method. Adducts of cinnamic acid (1,3- and 1,4-adducts) by reacting with C-C double of cinnamic acid.
特点和优势
This tert-BuLi formulation in PAO/hexanes is:
- Considered non-pyrophoric demonstrated using EPA’s SW-846 Test Method 1050
- Maintains the same reactivity as traditional tert-BuLi reagents
- Compatible with traditional lithiation additives like KOtBu or TMEDA
- More bench stable than traditional tert-BuLi reagents
警示用语：
Danger
危险分类
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - Water-react 1
靶器官
Nervous system
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
88.7 °F
闪点(°C)
31.5 °C
法规信息
危险化学品
此项目有
商品
Non-pyrophoric t-BuLi and n-BuLi formulations offer robust reactivity with improved handling.
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