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Merck
CN

939560

Lithium nickel manganese cobalt oxide

lithium-niobate coated NMC811 cathode active material

别名:

LiNbO3-coated NMC811, NMC811

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关于此项目

经验公式(希尔记法):
LiNi0.8Mn0.1Co0.1O2
化学文摘社编号:
分子量:
97.28
UNSPSC Code:
12352303
NACRES:
NA.21
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grade

battery grade

Quality Level

assay

>99%

form

powder

mol wt

97.28 g/mol

composition

(LiN0.85Mn0.05Co0.1O2)

density

4.8 g/cm3 ((lit.))

application(s)

battery manufacturing

SMILES string

[Li].[O].[Mn].[Co].[Ni]

General description

Lithium niobate coated NMC811 is a powdered form of lithium nickel manganese cobalt oxide with a stoichiometry of 8:1:1 Ni:Mn:Co and a typical particle size of 4-10 microns. The particles are coated in 5-10 nm amorphous lithium niobate, less than 1 wt.%. Our NMC811 has a minimum nickel content of 80.0% of the metal content (≥48.2 wt% overall), translating to a nickel-rich composition between NMC811 and NMC85:05:10.

Application

Lithium niobium oxide-coated NMC811 is a high-performance cathode material for solid-state and high-voltage lithium-ion batteries (LIBs). With 80% nickel content, NMC811 offers superior specific energy compared to NMC111, NMC532, or NMC622. The LiNbO3 coating enhances cathode stability by protecting the electrode and electrolyte from undesired reactions. Research suggests that this coating reduces capacity fade over time and restricts the release of metal ions from the NMC cathode, mitigating reactions with the electrolyte. The LiNbO3 "insertion layer" further improves rate capability by minimizing the space charge layer barrier at the electrolyte/cathode interface, leading to enhanced Li diffusion and reduced electrode polarization.

Features and Benefits

•NMC811 gives high specific energy density
•LiNbO3 coating safeguards cathode and electrolyte, enhancing coulombic efficiency
•LiNbO3 insertion layer enhances rate capability


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Hazard Classifications

Carc. 2 - Skin Sens. 1

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Not applicable

flash_point_c

Not applicable

存储类别

13 - Non Combustible Solids



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分析证书(COA)

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实验方案

Analysis of high- to moderate-nickel cathode materials for lithium-ion batteries, focusing on performance, stability, and structural characteristics.

Guide for fabricating NMC811 cathode electrodes, detailing procedures for optimal performance in lithium-ion batteries.

商品

ICP-MS workflow demonstrating the use of single- and multi-element standard mixes for accurate elemental analysis of lithium-ion battery cathode materials.


Lithium Niobate for Fast Cycling in Li-ion Batteries: Review and New Experimental Results
Huger E, et al.
Batteries, 9(5), 244-244 (2023)



全球贸易项目编号

货号GTIN
939560-25G04065272375313