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Merck
CN

939617

Sigma-Aldrich

[IPent-H]2Pd2Cl6

greener alternative

≥95%, powder, crystals or chunks

别名:

Bis-(1,3-bis(2,6-di(pentan-3-yl)phenyl)-1H-imidazol-3-ium)-hexachloropalladate

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About This Item

经验公式（希尔记法）:
C70H106Cl6N4Pd2
分子量:
1429.18

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Product Name

[IPent-H]2Pd2Cl6, ≥95%

质量水平

100

方案

≥95%

表单

powder, crystals or chunks

反应适用性

reagent type: catalyst
core: palladium
reaction type: Buchwald-Hartwig Amination
reagent type: catalyst
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: catalyst
core: palladium
reaction type: Cross Couplings
reagent type: catalyst
core: palladium
reaction type: Heck Reaction
reagent type: catalyst
core: palladium
reaction type: Hiyama Coupling
reagent type: catalyst
core: palladium
reaction type: Negishi Coupling
reagent type: catalyst
core: palladium
reaction type: Sonogashira Coupling
reagent type: catalyst
core: palladium
reaction type: Stille Coupling
reagent type: catalyst
core: palladium
reaction type: Suzuki-Miyaura Coupling

环保替代产品特性

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

颜色

white to very dark yellow-orange

环保替代产品分类

Aligned

SMILES字符串

CCC(C(C=CC=C1C(CC)CC)=C1[N+]2=CN(C3=C(C(CC)CC)C=CC=C3C(CC)CC)C=C2)CC.Cl[Pd]4(Cl)[ClH][Pd](Cl)(Cl)[ClH]4.CCC(C(C=CC=C5C(CC)CC)=C5[N+]6=CN(C7=C(C(CC)CC)C=CC=C7C(CC)CC)C=C6)CC

InChI

GIKNOYGRKZIYDU-UHFFFAOYSA-J

InChI key

InChI=1S/2C35H53N2.4ClH.2Cl.2Pd/c2*1-9-26(10-2)30-19-17-20-31(27(11-3)12-4)34(30)36-23-24-37(25-36)35-32(28(13-5)14-6)21-18-22-33(35)29(15-7)16-8;;;;;;;;/h2*17-29H,9-16H2,1-8H3;4*1H;;;;/q2*+1;;;;;;;2*+2/p-4

相关类别

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
[IPent-H]2Pd2Cl6 is an ionic tetrachloropalladate complex containing 2 equivalents of the cationic imadazolium ligand 1,3-bis(2,6-di(pentan-3-yl)phenyl)-1H-imidazol-3-ium.

应用

Upon treatmeant with a suitable base, a catalytically active Pd-NHC complex can be generated in-situ. Suitable for use in difficult Suzuki-Miyaura and Buchwald-Hartwig cross-couplings reactions of aryl chlorides, and trans-amidation cross-coupling reactions of esters and amides.
New NHC-Pd complexes for cross-coupling of challenging aryl chlorides

特点和优势

[IPent-H]2Pd2Cl6 offers similar or greater performance to other similar Pd-NHC precatalysts available while offering several major advatages:
  • The precatalyst avoids the use of ′throw away′ stabilizing ligands often used in similar Pd-NHC complexes.
  • The more sustainable synthesis of [IPent-H]2Pd2Cl6 compared to similar Pd-NHC complexes makes the product a more sustainable choice.
  • A competitive price, with a higher Pd percentage than other Pd-NHC catalysts.

象形图

Exclamation markEnvironment
GHS07,GHS09

警示用语：

Warning

危险声明

H302,H319,H411

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCW5784

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