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Merck
CN

941875

Sulfonated poly(ether ether ketone)

proton conducting polymer, degree of sulfonation 90%

别名:

Polyaromatic sulfonic acid, SPEEK, Sulfonated PEEK, Sulfonated aromatic polymer, Sulfonated poly(arylene ether sulfone) ionomer

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线性分子式:
(C19H12O6S)n(C19H12O3)m
UNSPSC Code:
13111024
NACRES:
NA.21
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InChI

InChI=1S/C40H30O9S/c1-26-3-5-27(6-4-26)39(41)28-7-13-31(14-8-28)47-33-19-21-34(22-20-33)48-32-15-9-29(10-16-32)40(42)30-11-17-35(18-12-30)49-37-24-23-36(46-2)25-38(37)50(43,44)45/h3-25H,1-2H3,(H,43,44,45)

SMILES string

COC1=CC(S(=O)(O)=O)=C(OC2=CC=C(C(C3=CC=C(OC4=CC=C(OC5=CC=C(C(C6=CC=C(C)C=C6)=O)C=C5)C=C4)C=C3)=O)C=C2)C=C1

form

powder or chunks (or fibers)

mol wt

100-200 kDa

color

white to yellow-brown

functional group

sulfonic acid

polymer architecture

shape: linear

Quality Level

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General description

Sulfonated poly(ether ether ketone) (SPEEK) is a modified form of polyetheretherketone (PEEK), where sulfonic acid groups are incorporated into the polymer backbone. This modification results in a high-performance polymer with enhanced properties. The SPEEK described here has a high molecular weight of 150 kDa and a high degree of sulfonation at 90%. These characteristics endow SPEEK with excellent thermal and chemical stability, high proton conductivity, and strong resistance to degradation even under harsh conditions. The integration of sulfonic acid groups significantly improves SPEEK′s performance in specialized applications, making it a versatile material in advanced technologies.

Application

Sulfonated poly(ether ether ketone) (SPEEK) is highly valued across several advanced applications due to its exceptional properties.

  • In fuel cell technology, SPEEK serves as an effective proton exchange membrane (PEM) . As a PEM, it facilitates the transport of protons from the anode to the cathode while preventing the mixing of reactant gases. Its excellent thermal and chemical stability allows it to withstand the high temperatures and corrosive environments typical of fuel cell operations. The high proton conductivity of SPEEK enhances the overall efficiency and performance of fuel cells.
  • In water purification and desalination processes [], SPEEK membranes utilize their sulfonic acid groups to enable efficient ion transport. This property is critical in techniques like reverse osmosis and electrodialysis, where the separation of ions and impurities from water is essential. Beyond these applications, SPEEK′s combination of thermal resistance, chemical durability, and proton conductivity makes it useful in other areas like sensing, aerospace, automotive, and electronics industries.

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