941875
Sulfonated poly(ether ether ketone)
proton conducting polymer, degree of sulfonation 90%
别名:
Polyaromatic sulfonic acid, SPEEK, Sulfonated PEEK, Sulfonated aromatic polymer, Sulfonated poly(arylene ether sulfone) ionomer
质量水平
表单
powder or chunks (or fibers)
分子量
100-200 kDa
颜色
white to yellow-brown
官能团
sulfonic acid
聚合物结构设计
shape: linear
SMILES字符串
COC1=CC(S(=O)(O)=O)=C(OC2=CC=C(C(C3=CC=C(OC4=CC=C(OC5=CC=C(C(C6=CC=C(C)C=C6)=O)C=C5)C=C4)C=C3)=O)C=C2)C=C1
InChI
InChI=1S/C40H30O9S/c1-26-3-5-27(6-4-26)39(41)28-7-13-31(14-8-28)47-33-19-21-34(22-20-33)48-32-15-9-29(10-16-32)40(42)30-11-17-35(18-12-30)49-37-24-23-36(46-2)25-38(37)50(43,44)45/h3-25H,1-2H3,(H,43,44,45)
一般描述
Sulfonated poly(ether ether ketone) (SPEEK) is a modified form of polyetheretherketone (PEEK), where sulfonic acid groups are incorporated into the polymer backbone. This modification results in a high-performance polymer with enhanced properties. The SPEEK described here has a high molecular weight of 150 kDa and a high degree of sulfonation at 90%. These characteristics endow SPEEK with excellent thermal and chemical stability, high proton conductivity, and strong resistance to degradation even under harsh conditions. The integration of sulfonic acid groups significantly improves SPEEK′s performance in specialized applications, making it a versatile material in advanced technologies.
应用
Sulfonated poly(ether ether ketone) (SPEEK) is highly valued across several advanced applications due to its exceptional properties.
- In fuel cell technology, SPEEK serves as an effective proton exchange membrane (PEM) . As a PEM, it facilitates the transport of protons from the anode to the cathode while preventing the mixing of reactant gases. Its excellent thermal and chemical stability allows it to withstand the high temperatures and corrosive environments typical of fuel cell operations. The high proton conductivity of SPEEK enhances the overall efficiency and performance of fuel cells.
- In water purification and desalination processes [], SPEEK membranes utilize their sulfonic acid groups to enable efficient ion transport. This property is critical in techniques like reverse osmosis and electrodialysis, where the separation of ions and impurities from water is essential. Beyond these applications, SPEEK′s combination of thermal resistance, chemical durability, and proton conductivity makes it useful in other areas like sensing, aerospace, automotive, and electronics industries.
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