94327
Deoxo-Fluor 溶液
50% in THF
别名:
双(2-甲氧基乙基)氨基三氟化硫 溶液
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关于此项目
经验公式（希尔记法）:
C6H14F3NO2S
化学文摘社编号:
分子量:
221.24
UNSPSC Code:
12352101
PubChem Substance ID:
MDL number:
Other Notes
具有高热稳定性的氟化剂
Application
Reactant for:
- Fluorination reactions
- Preparation of fluorinated catechols via Umpolung based nucleophilic deoxyfluorination
- Preparation of imidazole derivatives as CXCR3 antagonists
- Ring expansion reactions
- Synthesis of acyl azides from carboxylic acids
- Aldehydes or ketones from carboxylic acids and Grignard reagents via in situ generation of Weinreb amides
Legal Information
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Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3 - Water-react 2
target_organs
Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
<50.0 °F - closed cup
flash_point_c
< 10 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Fluorinating agent with high thermal stability.
S. Lal-Gauri et al.
The Journal of Organic Chemistry, 64, 7048-7048 (1999)
Lal et al.
The Journal of organic chemistry, 65(16), 4830-4832 (2000-08-24)
A variety of thiocarbonyl derivatives (thioketone, thioester, thioamide, dithioester, and dithiocarbamate) were converted to the corresponding gem-difluorides in excellent yields on reaction with the fluorinating agent, bis(2-methoxyethyl)aminosulfur trifluoride, in the presence of SbCl(3).
R.P. Singh, J.M. Shreeve
Journal of Fluorine Chemistry, 116, 23-23 (2002)
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