95020
乙烯基膦酸二甲酯
≥95% (GC)
别名:
1-二甲氧基磷酰乙烯, 乙烯基(二甲氧基)氧膦, 乙烯基磷酸二甲酯, 二甲基乙烯基膦酸酯
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关于此项目
线性分子式:
CH2=CHPO(OCH3)2
化学文摘社编号:
分子量:
136.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
225-076-4
Beilstein/REAXYS Number:
1748827
MDL number:
产品名称
乙烯基膦酸二甲酯, ≥95% (GC)
Quality Level
InChI key
CQCXMYUCNSJSKG-UHFFFAOYSA-N
InChI
1S/C4H9O3P/c1-4-8(5,6-2)7-3/h4H,1H2,2-3H3
SMILES string
COP(=O)(OC)C=C
assay
≥95% (GC)
form
liquid
refractive index
n20/D 1.430-1.435
bp
197-202 °C (lit.)
density
1.146 g/mL at 20 °C (lit.)
storage temp.
2-8°C
Application
- Improving the Corrosion Resistance of Lead in H2SO4 by Addition of Phosphoric and Phosphonic Compounds: 研究讨论二甲基-乙烯基磷酸酯如何增强铅板栅电池(lead grid batteries)的耐腐蚀性(S Khatbi et al., 2016)′。
- Relay Cross Metathesis Reactions of Vinylphosphonates: 该文讨论二甲基-乙烯基磷酸酯与纯净甲基咪唑的反应，说明一条用于生产珍贵有机盐的潜在路径(RK Malla et al., 2014)。
- Enhanced Flame Retardance of Polyacrylonitrile with Dimethyl Vinylphosphonate：探讨如何提高纺织品的阻燃性，对于材料安全应用有重要意义(X Dong et al., 2021)。
Other Notes
乙烯基膦酸酯是进行 Michael 加成反应生成烷基膦酸酯的多功能试剂；合成氮杂环丙烷-2-膦酸酯，有效制备 α-氨基膦酸酯
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
208.4 °F - closed cup
flash_point_c
98 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
N. Minova et al.
Bulletin of the Chemical Society of Japan, 60, 1761-1761 (1987)
J. Zygmunt
Tetrahedron, 41, 4979-4979 (1985)
S. Mirza et al.
Helvetica Chimica Acta, 67, 1562-1562 (1984)
F. Nicotra et al.
Journal of the Chemical Society. Chemical Communications, 5-5 (1984)
Amir Shafiee Kisomi et al.
Ultrasonics sonochemistry, 44, 129-136 (2018-04-24)
In this research, a novel Sn(II)-imprinted poly(dimethyl vinylphosphonate) nanopowder (Sn(II)-IPDMVPN) was prepared using Sn2+, dimethyl vinylphosphonate, azobis isobutyronitril and ethylene glycol dimethacrylate as the template, ligand, initiator and cross linker, respectively. The non-imprinted poly(dimethyl vinylphosphonate) nanopowder (NIPDMVPN) was also synthesized
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