A24001
丙烯醛缩二乙醇
96%
别名:
3,3-二乙氧基丙烯
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线性分子式:
CH2=CHCH(OCH2CH3)2
化学文摘社编号:
分子量:
130.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-276-0
Beilstein/REAXYS Number:
1701567
MDL number:
产品名称
丙烯醛缩二乙醇, 96%
InChI key
MCIPQLOKVXSHTD-UHFFFAOYSA-N
InChI
1S/C7H14O2/c1-4-7(8-5-2)9-6-3/h4,7H,1,5-6H2,2-3H3
SMILES string
CCOC(OCC)C=C
assay
96%
form
liquid
refractive index
n20/D 1.398 (lit.)
bp
125 °C (lit.)
density
0.854 g/mL at 25 °C (lit.)
Quality Level
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Application
丙烯醛二乙基缩醛广泛用于进行化学选择性 Heck 芳基化，合成 3-芳基丙酸酯或肉桂醛衍生物。
它也可用作合成天然产物如 (-)-(Z)-脱氧普卡灵、(-)-Laulimalide、botryodiplodin、neolaulimalide 和 isolaulimalide 的前体之一。
它也可用作合成天然产物如 (-)-(Z)-脱氧普卡灵、(-)-Laulimalide、botryodiplodin、neolaulimalide 和 isolaulimalide 的前体之一。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
59.0 °F - closed cup
flash_point_c
15 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis of (-)?(Z)?Deoxypukalide.
Donohoe TJ et al.
Angewandte Chemie (International Edition in English), 47(38), 7314-7316 (2008)
Acrolein Diethyl Acetal: A Three?Carbon Homologating Reagent for the Synthesis of β?Arylpropanoates and Cinnamaldehydes by Heck Reaction Catalyzed by a Kaiser Oxime Resin Derived Palladacycle.
Alacid E and Najera C
The Journal of Organic Chemistry, 2008(18), 3102-3106 (2008)
Stefano Parisotto et al.
Organic & biomolecular chemistry, 15(4), 884-893 (2017-01-04)
As part of our ongoing work on the synthesis of a new class of plant hormones named Strigolactones (SLs) and their analogues, we became interested in tracing bioactive molecules with red emitting BODIPY fluorophores in order to unravel signaling and
Mohammad Saidur Rhaman et al.
Plant & cell physiology, 61(5), 967-977 (2020-03-08)
Myrosinase (β-thioglucoside glucohydrolase, enzyme nomenclature, EC 3.2.1.147, TGG) is a highly abundant protein in Arabidopsis guard cells, of which TGG1 and TGG2 function redundantly in abscisic acid (ABA)- and methyl jasmonate-induced stomatal closure. Reactive carbonyl species (RCS) are α,β-unsaturated aldehydes
An efficient palladium-catalyzed synthesis of cinnamaldehydes from acrolein diethyl acetal and aryl iodides and bromides.
Battistuzzi G, et al.
Organic Letters, 5(5), 777-780 (2003)
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