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A24001

丙烯醛缩二乙醇

Name: 丙烯醛缩二乙醇
Brand: ALDRICH

96%

别名:

3,3-二乙氧基丙烯

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关于此项目

线性分子式:

CH₂=CHCH(OCH₂CH₃)₂

化学文摘社编号:

3054-95-3

分子量:

130.18

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24890652

EC Number:

221-276-0

Beilstein/REAXYS Number:

1701567

MDL number:

MFCD00009239

Assay:

96%

Form:

liquid

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属性

Quality Level

200

assay

96%

form

liquid

refractive index

n20/D 1.398 (lit.)

bp

125 °C (lit.)

density

0.854 g/mL at 25 °C (lit.)

SMILES string

CCOC(OCC)C=C

InChI

1S/C7H14O2/c1-4-7(8-5-2)9-6-3/h4,7H,1,5-6H2,2-3H3

InChI key

MCIPQLOKVXSHTD-UHFFFAOYSA-N

说明

Application

丙烯醛二乙基缩醛广泛用于进行化学选择性 Heck 芳基化，合成 3-芳基丙酸酯或肉桂醛衍生物。

它也可用作合成天然产物如 (-)-(Z)-脱氧普卡灵、(-)-Laulimalide、botryodiplodin、neolaulimalide 和 isolaulimalide 的前体之一。

pictograms

GHS02,GHS07

signalword

Danger

hcodes

H225,H319

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2

存储类别

3 - Flammable liquids

flash_point_f

59.0 °F - closed cup

flash_point_c

15 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

pcodes

P210 - P233 - P240 - P241 - P280 - P305 + P351 + P338

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

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Synthesis of (-)?(Z)?Deoxypukalide.

Donohoe TJ et al.

Angewandte Chemie (International Edition in English), 47(38), 7314-7316 (2008)

Acrolein Diethyl Acetal: A Three?Carbon Homologating Reagent for the Synthesis of β?Arylpropanoates and Cinnamaldehydes by Heck Reaction Catalyzed by a Kaiser Oxime Resin Derived Palladacycle.

Alacid E and Najera C

The Journal of Organic Chemistry, 2008(18), 3102-3106 (2008)

Heck functionalization of an asymmetric aza-BODIPY core: synthesis of far-red infrared probes for bioimaging applications.

Stefano Parisotto et al.

Organic & biomolecular chemistry, 15(4), 884-893 (2017-01-04)

As part of our ongoing work on the synthesis of a new class of plant hormones named Strigolactones (SLs) and their analogues, we became interested in tracing bioactive molecules with red emitting BODIPY fluorophores in order to unravel signaling and

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全球贸易项目编号

货号	GTIN
A24001-100G	04061837016042
A24001-25G	04061833350140