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Merck
CN

A30702

烯丙基氯

reagent grade, 98%

别名:

3-氯-1-丙烯, 氯丙烯

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关于此项目

线性分子式:
CH2=CHCH2Cl
化学文摘社编号:
分子量:
76.52
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-457-6
Beilstein/REAXYS Number:
635704
MDL number:
Assay:
98%
Form:
liquid
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grade

reagent grade

Quality Level

vapor density

2.6 (vs air)

vapor pressure

20.58 psi ( 55 °C), 5.71 psi ( 20 °C)

assay

98%

form

liquid

expl. lim.

11.2 %

refractive index

n20/D 1.414 (lit.)

bp

44-46 °C (lit.)

mp

−130 °C (lit.)

density

0.939 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

ClCC=C

InChI

1S/C3H5Cl/c1-2-3-4/h2H,1,3H2

InChI key

OSDWBNJEKMUWAV-UHFFFAOYSA-N

Application

氯丙烯可用作反应剂:
  • 通过原位生成的苯炔的烯丙基炔基化反应得到1-烯丙基-2-炔基苯衍生物。
  • 使用钌催化剂与脂肪酸甲酯反应生成α,ω-双官能中间体。
  • 通过Sn/I2催化的羰基化合物的Barbier烯丙基反应制备高烯丙醇化合物。

Other Notes

货号A30702-4X1L的产品即将停产。请订购A30702-1L单瓶装,因为其物理参数与上述产品本质相同。


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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

target_organs

Nervous system,Liver,Kidney, Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-25.6 °F

flash_point_c

-32 °C

ppe

Eyeshields, Faceshields, Gloves

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Sn/I2 Mediated allylation of carbonyl compounds with allyl (crotyl) halide in water
Zhou Y, et al.
ARKIVOC (Gainesville, FL, United States), 11(1), 142-153 (2008)
Airong Xu et al.
Scientific reports, 9(1), 11518-11518 (2019-08-10)
The utilization of cellulose in industrial applicat is of great significance to sustainable development of human society and reducing dependence on dwindling fossil resources. Nevertheless, this utilization of cellulose has actually been limited due to its insolubilization. Here, novel solvents
Palladium-Catalyzed Allylalkynylation of Benzynes: A Highly Efficient Route to Substituted 1-Allyl-2-alkynylbenzenes
Jeganmohan M and Cheng C-H
Organic Letters, 6(16), 2821-2824 (2004)



全球贸易项目编号

货号GTIN
A30702-1L04061833360231
A30702-2.5L04061833360248
A30702-4L04061837867460
A30702-500ML04061833360255
A30702-2L04061837867453