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Merck
CN

A32608

烯丙基缩水甘油醚

≥99%

别名:

1-烯丙氧基-2,3-环氧丙烷, 烯丙基-2,3-环氧丙醚

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关于此项目

经验公式(希尔记法):
C6H10O2
化学文摘社编号:
分子量:
114.14
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
203-442-4
Beilstein/REAXYS Number:
105871
MDL number:
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form

liquid

InChI key

LSWYGACWGAICNM-UHFFFAOYSA-N

InChI

1S/C6H10O2/c1-2-3-7-4-6-5-8-6/h2,6H,1,3-5H2

SMILES string

C=CCOCC1OC1

vapor density

3.9 (vs air)

vapor pressure

4.7 mmHg ( 25 °C)

assay

≥99%

refractive index

n20/D 1.433 (lit.)

bp

154 °C (lit.)

density

0.962 g/mL at 25 °C (lit.)

Quality Level

General description

烯丙基缩水甘油醚(AGE)可作为聚(烯丙基缩水甘油醚)阴离子开环聚合反应的合成单体。它在工业上可以通过烯丙醇和环氧氯丙烷反应制备而成。

Application

AGE可用作氢化硅烷化制备粘附性表面的末端环氧基团。它还可用于合成锂电池用聚电解质。
用于氢化硅烷化,包括H2PtCl6·xH2O(货号206083)催化的硅氧烷成为环氧硅氧烷的氢化硅烷化。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

134.6 °F - closed cup

flash_point_c

57 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

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Y Koyama et al.
Bioconjugate chemistry, 7(3), 298-301 (1996-05-01)
Novel poly(ethylene glycol) (PEG) derivatives having pendant amino groups were prepared by copolymerization of allyl glycidyl ether with ethylene oxide followed by chemical modification of the double bond side chains. Dropwise addition of the mixture of monomers to the anionic
Minimally adhesive polymer surfaces prepared from star oligosiloxanes and star oligofluorosiloxanes
Grunlan MA, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 44(8), 2551-2566 (2006)
Challa Lahari et al.
Langmuir : the ACS journal of surfaces and colloids, 26(2), 1096-1106 (2009-12-10)
Effects of changes in hydrophobicity of polymeric support on structure and activity of alpha-chymotrypsin (E.C. 3.4.21.1) have been studied with copolymers of allyl glycidyl ether (AGE) and ethylene glycol dimethacrylate (EGDM) with increasing molar ratio of EGDM to AGE (cross-link
Bhalchandra K Vaidya et al.
Bioresource technology, 99(9), 3623-3629 (2007-09-04)
Macroporous polymer particles containing surface epoxy groups were synthesized for immobilization of Candida rugosa lipase (CRL). The effect of incorporation of two different sets of monomers [allyl glycidyl ether (AGE) and glycidyl methacrylate (GMA)] and the effect of crosslinking density
Allyl glycidyl ether-based polymer electrolytes for room temperature lithium batteries
Barteau KP, et al.
Macromolecules, 46(22), 8988-8994 (2013)

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