A53605
二苯甲胺
97%
别名:
α-氨基二苯甲烷
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线性分子式:
(C6H5)2CHNH2
化学文摘社编号:
分子量:
183.25
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-032-2
Beilstein/REAXYS Number:
776434
MDL number:
产品名称
二苯甲胺, 97%
InChI key
MGHPNCMVUAKAIE-UHFFFAOYSA-N
InChI
1S/C13H13N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H,14H2
SMILES string
NC(c1ccccc1)c2ccccc2
assay
97%
form
liquid
refractive index
n20/D 1.595 (lit.)
bp
295 °C (lit.)
mp
12 °C (lit.)
density
1.063 g/mL at 25 °C (lit.)
Quality Level
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Abdul M Seayad et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(18), 5693-5700 (2012-03-23)
A robust heterogeneous self-supported chiral titanium cluster (SCTC) catalyst and its application in the enantioselective imine-cyanation/Strecker reaction is described under batch and continuous processes. One of the major hurdles in the asymmetric Strecker reaction is the lack of availability of
Fang-Kun Deng et al.
Journal of peptide science : an official publication of the European Peptide Society, 16(10), 545-550 (2010-09-09)
Well-characterized resins of high purity are critical for effective solid phase peptide synthesis (SPPS). The quality of commercial (4-methyl)benzhydrylamine-resin (MBHA-resin), used for the synthesis of peptide amides, is not consistent and residual ketone functionalities are frequently present. Such ketone or
Benzhydrylamine linker grafting: a strategy for the improved synthesis of C-terminal peptide amides.
Dianne Alewood et al.
Journal of peptide science : an official publication of the European Peptide Society, 16(10), 551-557 (2010-09-24)
The standard p-MBHA resin used during Boc-chemistry synthesis of peptides carrying C-terminal carboxamides is compromised by batch-to-batch variations in its performance. This can cause artificially 'difficult' couplings during peptide chain assembly, which may ultimately lead to failed syntheses given the
Regina S H Carvalho et al.
Journal of biochemical and biophysical methods, 57(1), 75-83 (2003-07-02)
Benzhydrylamine-resin (BHAR), a copolymer of styrene-divinylbenzene containing phenylmethylamine groups, used as solid support for peptide synthesis, was examined regarding physicochemical and anion exchanger chromatographic properties. The greater the ionic strength of the medium the poorer the solvation of beads. This
N A Goud et al.
Journal of bone and mineral research : the official journal of the American Society for Bone and Mineral Research, 6(8), 781-789 (1991-08-01)
We have chemically synthesized the full-length, 84 amino acid, human parathyroid hormone (hPTH) on a greater than 100 mg scale by the Merrifield solid-phase technique of stepwise peptide synthesis using a benzhydrylamine support. The peptide was purified by high-performance liquid
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