A70704
(1R,2R)-(-)-2-氨基-1-(4-硝基苯基)-1,3-丙二醇
99%
别名:
D-(-)-苏-1-对硝基苯基-2-氨基-1,3-丙二醇, 氯霉素碱
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关于此项目
线性分子式:
HOCH2CH(NH2)CH(C6H4NO2)OH
化学文摘社编号:
分子量:
212.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
EC Number:
211-938-7
MDL number:
Assay:
99%
Form:
powder
Quality Level
assay
99%
form
powder
optical activity
[α]25/D −30°, c = 1 in 6 M HCl
mp
163-165 °C (lit.)
SMILES string
N[C@H](CO)[C@H](O)c1ccc(cc1)[N+]([O-])=O
InChI
1S/C9H12N2O4/c10-8(5-12)9(13)6-1-3-7(4-2-6)11(14)15/h1-4,8-9,12-13H,5,10H2/t8-,9-/m1/s1
InChI key
OCYJXSUPZMNXEN-RKDXNWHRSA-N
Application
（1R，2R）-（-）-2-氨基-1-（4-硝基苯基）-1,3-丙二醇可用于通过N，N-二甲基化，制备（1R，2R）-（-）-2-二甲基氨基-1-（4-硝基苯基）-1,3-丙二醇。 它也可以用作合成原料，对（1R，2R）-1,3-二乙酰氧基-1-（4-硝基苯基）-2-丙基异硫氰酸酯[（R，R）-DANI]进行合成。
存储类别
11 - Combustible Solids
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
ppe
dust mask type N95 (US), Eyeshields, Gloves
Development of new isothiocyanate-based chiral derivatizing agent for amino acids.
Peter M, et al.
Chromatographia, 50(5-6), 373-375 (1999)
(1R, 2R)-(-)-2-Dimethylamino-1-(4-nitrophenyl)-1, 3-propanediol/l-proline cocatalyzed enantioselective Morita-Baylis-Hillman reaction.
Tang H, et al.
Catalysis Communications, 8(11), 1811-1814 (2007)
D K Zheng et al.
Yao xue xue bao = Acta pharmaceutica Sinica, 25(6), 430-434 (1990-01-01)
Threo (-) or (+)-1-(p-nitrophenyl)-1,3-dihydroxypropylamine-2 was found to be a useful resolving agent for racemic gossypol. The optical and chemical stability of the condensate of enantiomeric gossypols with the titled amine and the great difference in the Rf values on TLC
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| A70704-25G | 04061833383438 |
| A70704-10G | 04061833383421 |