A71301
2-氨基苯酚
99%
别名:
(2-羟苯基)胺, 1-羟基-2-氨基苯, 2-氨基-1-羟基苯, 2-氨基苯基乙醇, 2-氨基苯酚, 2-羟基苯胺, 2-羟苯胺, o-氨基羟基苯, o-羟基苯胺, o-羟苯胺
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关于此项目
线性分子式:
H2NC6H4OH
化学文摘社编号:
分子量:
109.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-431-1
Beilstein/REAXYS Number:
606075
MDL number:
Assay:
99%
Form:
powder
InChI key
CDAWCLOXVUBKRW-UHFFFAOYSA-N
InChI
1S/C6H7NO/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2
SMILES string
Nc1ccccc1O
assay
99%
form
powder
Quality Level
mp
170-175 °C (lit.)
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Application
2-氨基苯酚可用于合成：
- 与β氨基醇在Pd/C-I2催化下通过氧化环羰基化反应合成2-噁唑烷酮衍生物。
- 与亚水杨基-4-氨基安替比林合成席夫碱过渡金属(II)配合物。
- 在富氧气氛、活性碳催化下与醛合成2-芳基苯并噁唑。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Muta. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 2
flash_point_f
334.4 °F - closed cup
flash_point_c
168 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
此项目有
Synthesis, spectroscopic characterization, redox, and biological screening studies of some Schiff base transition metal (II) complexes derived from salicylidene-4-aminoantipyrine and 2-aminophenol/2-aminothiophenol.
Raman N, et al.
Synth. React. Inorg. Met.-Org. Chem. , 31(7), 1249-1270 (2001)
Synthesis of 2-oxazolidinone catalyzed by palladium on charcoal: a novel and highly effective heterogeneous catalytic system for oxidative cyclocarbonylation of β -aminoalcohols and 2-aminophenol.
Li F and Xia C
J. Catal., 227(2), 542-546 (2004)
Bifu Liu et al.
Chemical communications (Cambridge, England), 48(93), 11446-11448 (2012-10-23)
A robust route to 4-amine-benzo[b][1,4]oxazepines relying upon a palladium-catalyzed tandem reaction of o-aminophenols, bromoalkynes and isocyanides has been developed. This chemistry presumably proceeds through the migratory insertion of isocyanides into the vinyl-palladium intermediate as a key step.
Michael M Bittner et al.
Journal of the American Chemical Society, 134(12), 5460-5463 (2012-03-16)
The oxidative ring cleavage of aromatic substrates by nonheme Fe dioxygenases is thought to involve formation of a ferrous-(substrate radical) intermediate. Here we describe the synthesis of the trigonal-bipyramdial complex Fe((Ph2)Tp)(ISQ(tBu)) (2), the first synthetic example of an iron(II) center
Yoshinori Endo et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(43), 13609-13613 (2012-09-13)
Aerobic oxidation: in a biomimetic approach, a mixture of redox catalysts forms couples that effect the aerobic oxidation of a mixture of benzylamine and 2-aminophenol derivatives to give the corresponding benzoxazoles. This biomimetic oxidation proceeds smoothly under mild conditions and
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