Merck
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文件

安全信息

A8524

Sigma-Aldrich

苯胺 盐酸盐

≥99%

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别名:
Anilinium chloride, Benzenamine hydrochloride, Phenylamine hydrochloride, Phenylammonium chloride
线性分子式:
C6H5NH2 · HCl
CAS号:
142-04-1
分子量:
129.59
Beilstein:
3593823
EC 号:
205-519-8
MDL编号:
MFCD00012958
PubChem化学物质编号:
57653890
NACRES:
NA.22

蒸汽密度

4.46 (vs air)

质量水平

200

检测方案

≥99%

形式

crystals

mp

196-198 °C (lit.)

SMILES字符串

Cl.Nc1ccccc1

InChI

1S/C6H7N.ClH/c7-6-4-2-1-3-5-6;/h1-5H,7H2;1H

InChI key

MMCPOSDMTGQNKG-UHFFFAOYSA-N

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生化/生理作用

苯胺的急性毒性与其体内活化生成4-羟基苯胺并与血红蛋白形成加合物有关。在红细胞中，这与铁的释放和高铁血红蛋白的积累以及溶血性贫血和脾脏炎症的发展有关。长期给药经常在脾脏中观察到肿瘤形成。

警示用语：

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Muta. 2 - Skin Sens. 1 - STOT RE 1

储存分类代码

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

381.2 °F - closed cup

闪点(°C)

194 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

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This study presents the preparation of membranes of polylactic acid (PLLA), polyacrylonitrile (PAN) and their corresponding membranes coated with polyaniline (PANI) for the adsorption of methylene blue (MB). Scanning electron microscopy micrographs reveal that all the membranes exhibit nanofibrous morphology.
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Faraday discussions, 157, 165-179 (2012-12-13)
Femtosecond time-resolved photoelectron imaging is employed to investigate ultrafast electronic relaxation in aniline, a prototypical aromatic amine. The molecule is excited at wavelengths between 269 and 238 nm. We observe that the S2(pi3s/pi sigma*) state is populated directly during the
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Journal of the American Chemical Society, 134(46), 18924-18927 (2012-11-08)
A novel and efficient copper-catalyzed azidation reaction of anilines via C-H activation has been developed. This method, in which the primary amine acts as a directing group by coordinating to the metal center, provides ortho azidation products regioselectively under mild
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Substituted 2-aminobiphenyls have been prepared from arylhydrazines and anilines via radical arylation reactions under simple oxidative conditions. The strong directing effect of the free and unprotonated amino functionality leads to high regioselectivities, and anilines have been shown to be significantly
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