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ALD00508

Yu Fluorination Ligand

≥95%

别名:

2,5,6,8-tetramethyl-3,4-dihydro-2H-pyrano[2,3-b]quinoline

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关于此项目

经验公式（希尔记法）:
C16H19NO
化学文摘社编号:
1771764-64-7
分子量:
241.33
MDL number:
MFCD29059851
UNSPSC Code:
41116155
PubChem Substance ID:
329772697
NACRES:
NA.22
Assay:
≥95%
Form:
powder
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Quality Segment

100

assay

≥95%

form

powder

reaction suitability

reagent type: catalyst, reagent type: ligand
reaction type: C-H Activation

SMILES string

CC1=C2C(OC(C)CC2)=NC3=C1C(C)=CC(C)=C3

InChI

1S/C16H19NO/c1-9-7-10(2)15-12(4)13-6-5-11(3)18-16(13)17-14(15)8-9/h7-8,11H,5-6H2,1-4H3

InChI key

LOKRNFHHPZEJLL-UHFFFAOYSA-N

General description

Yu Fluorination Ligand is widely employed for the chemoselective functionalization of sp2- and sp3 C-H bonds.

Application

The Yu Fluorination Ligand in tandem with Selectfluor(R) (Aldrich 439479) under palladium catalysis can promote direct fluorination of C(sp3)-H bonds stereoselectively. Yu and coworkers have displayed this on amino acid derivatives with directing group assistance from the Yu-Wasa Auxiliary (Aldrich 791806).

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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