ALD00596
N-((1S,2S)-1-(3,5-Di-tert-butylphenyl)-2-(quinolin-2-yl)butyl)acetamide
≥95%
别名:
Chiral acetyl-protected aminoethyl quinoline ligand, Et-APAQ
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关于此项目
Assay:
≥95%
Form:
powder or crystals
Quality Segment
assay
≥95%
form
powder or crystals
reaction suitability
reaction type: C-C Bond Formation, reagent type: catalyst, reagent type: ligand
reaction type: C-H Activation
SMILES string
N([C@@H]([C@H](CC)c2nc3c(cc2)cccc3)c1cc(cc(c1)C(C)(C)C)C(C)(C)C)C(=O)C
InChI
1S/C29H38N2O/c1-9-24(26-15-14-20-12-10-11-13-25(20)31-26)27(30-19(2)32)21-16-22(28(3,4)5)18-23(17-21)29(6,7)8/h10-18,24,27H,9H2,1-8H3,(H,30,32)/t24-,27-/m1/s1
InChI key
NZPXTQVMJQHEBG-SHQCIBLASA-N
Application
This chiral acetyl-protected aminoethyl quinoline (APAQ) ligand was developed by the Yu group for ligand-enabled acceleration of Pd-catalyzed enantioselective β-methylene C–H functionalization, which is important for the generation of β-chiral centers in asymmetric synthesis.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable