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Merck
CN

B32602

苄基三甲基氢氧化铵 溶液

40 wt. % in methanol

别名:

N,N,N-Trimethyl-N-benzylammonium hydroxide, N,N,N-trimethyl-1-phenylmethanaminium hydroxide, N,N,N-trimethylbenzenemethanaminium hydroxide, Triton B

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关于此项目

线性分子式:
C6H5CH2N(OH)(CH3)3
化学文摘社编号:
分子量:
167.25
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3917256
Concentration:
40 wt. % in methanol
Form:
liquid
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产品名称

苄基三甲基氢氧化铵 溶液, 40 wt. % in methanol

InChI

1S/C10H16N.H2O/c1-11(2,3)9-10-7-5-4-6-8-10;/h4-8H,9H2,1-3H3;1H2/q+1;/p-1

SMILES string

[OH-].C[N+](C)(C)Cc1ccccc1

InChI key

NDKBVBUGCNGSJJ-UHFFFAOYSA-M

form

liquid

concentration

40 wt. % in methanol

density

0.92 g/mL at 25 °C

Quality Level

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Application

苄基三甲基氢氧化铵溶液可用于:     
  • 作为nitroaldol缩合反应的催化剂
  • 作为结构导向剂,用于水热法合成富二氧化硅的铝硅酸盐沸石(菱沸石型)
  • 作为离子液体前体制备ZnO纳米结构颗粒

General description

苄基三甲基氢氧化铵溶液是一种季铵盐化合物,常用作有机合成中的碱。也用作几种聚合反应的碱性催化剂。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 1

target_organs

Eyes,Central nervous system

存储类别

3 - Flammable liquids

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup

ppe

Faceshields, Gloves, Goggles

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Purushothaman Gopinath et al.
The Journal of organic chemistry, 74(16), 6291-6294 (2009-07-22)
An efficient protocol is reported for the synthesis of thioesters from carboxylic acids with use of acyloxy phosphonium salts as intermediates and benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.
Weisheng Lin et al.
Analytica chimica acta, 583(1), 98-102 (2007-03-28)
The importance of benzyltriethyl ammonium chloride (BTEAC) in industrial applications has stimulated the development of a number of methods for its determination. In this paper, a high performance capillary electrophoresis (CE) method, coupled with an extraction technique for determining BTEAC
J M Sanders et al.
Xenobiotica; the fate of foreign compounds in biological systems, 25(3), 303-313 (1995-03-01)
1. Benzyltrimethylammonium chloride (BTMAC)-derived radioactivity was rapidly eliminated from the F344 rat and the B6C3F1 mouse following p.o. administration of 0.63-63 mg/kg of [ring-U-14C] BTMAC. Greater than 90% of the radioactivity was excreted in urine and faeces within 24-h post-dosing.
Li Zaijun et al.
Journal of AOAC International, 90(4), 1191-1196 (2007-09-01)
The ionic liquid 1-butyl-3-trimethylsilylimidazolium hexafluorophosphate, abbreviated as [C4tmsim][PF6], was developed as a novel medium for liquid-liquid extraction of lead(II) in water, in which dithizone was used as a metal chelator to form a neutral lead-dithizone complex. Under optimal conditions, the
Nicola H Davies et al.
Journal of chromatography. A, 1119(1-2), 11-19 (2006-01-03)
The retention and overloading properties for eight basic solutes and two quaternary ammonium compounds were studied over the pH range 2.7-10.0 using phosphate and carbonate buffers. At low pH, a hybrid inorganic-organic silica-ODS phase (XTerra RP-18, 15 cm x 0.46

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