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线性分子式:
BrC6H4OCH3
化学文摘社编号:
分子量:
187.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-252-1
Beilstein/REAXYS Number:
1237590
MDL number:
产品名称
4-溴苯甲醚, ≥99.0%
InChI key
QJPJQTDYNZXKQF-UHFFFAOYSA-N
InChI
1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
SMILES string
COc1ccc(Br)cc1
assay
≥99.0%
form
liquid
refractive index
n20/D 1.564 (lit.)
bp
223 °C (lit.)
mp
9-10 °C (lit.)
density
1.494 g/mL at 25 °C (lit.)
Quality Level
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Application
4-溴苯甲醚被用于合成芳基1,3-二酮。
General description
4-溴苯甲醚一种实用的溴化试剂。它是在HOBr与苯甲醚之间的反应中形成的反应产物。已有研究报道了由钳形钯复合物催化的4-溴苯甲醚与苯硼酸的Suzuki偶联反应。据报道,在室温离子液体中,4-溴苯甲醚与丙烯酸乙酯发生Heck反应,形成4-甲氧基肉桂酸。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 2
flash_point_f
201.2 °F
flash_point_c
94 °C
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
危险化学品
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J Vokurka et al.
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The methylotrophic yeast Pichia pastoris is widely used to produce recombinant proteins, taking advantage of this species' high-density cell growth and strong ability to secrete proteins. Circular plasmids containing the P. pastoris-specific autonomously replicating sequence (PARS1) permit transformation of P.
John D Sivey et al.
Environmental science & technology, 49(8), 4937-4945 (2015-03-25)
When bromide-containing waters are chlorinated, conventional wisdom typically assumes HOBr is the only active brominating agent. Several additional and often-overlooked brominating agents (including BrCl, Br2, BrOCl, Br2O) can form in chlorinated waters, albeit at generally lower concentrations than HOBr. The
Valdecir Farias Ximenes et al.
Journal of inorganic biochemistry, 146, 61-68 (2015-03-17)
Hypobromous acid (HOBr) is an inorganic acid produced by the oxidation of the bromide anion (Br(-)). The blood plasma level of Br(-) is more than 1,000-fold lower than that of chloride anion (Cl(-)). Consequently, the endogenous production of HOBr is
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