B57702
溴苯
ReagentPlus®, 99%
别名:
1-Bromobenzene, Bromobenzol, Monobromobenzene, Phenyl bromide
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关于此项目
经验公式（希尔记法）:
C6H5Br
化学文摘社编号:
分子量:
157.01
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-623-8
Beilstein/REAXYS Number:
1236661
MDL number:
Assay:
99%
Form:
liquid
vapor density
5.41 (vs air)
Quality Level
vapor pressure
10 mmHg ( 40 °C)
product line
ReagentPlus®
assay
99%
form
liquid
autoignition temp.
1051 °F
expl. lim.
36.5 %
refractive index
n20/D 1.559 (lit.)
bp
156 °C (lit.)
mp
−31 °C (lit.)
density
1.474 g/mL at 25 °C, 1.491 g/mL at 25 °C (lit.)
SMILES string
Brc1ccccc1
InChI
1S/C6H5Br/c7-6-4-2-1-3-5-6/h1-5H
InChI key
QARVLSVVCXYDNA-UHFFFAOYSA-N
General description
溴苯是一种芳基氯。它参与非活化和失活芳基氯化物的优化钯/金属氧化物体系催化的Heck反应。据报道，已有研究使用环钯配合物催化溴苯与苯乙烯的反应。它通过形成活性代谢物而诱导肝坏死。
Application
溴苯可作为交叉偶联反应的反应物（如Suzuki偶联反应）合成各种不对称联芳和Mizoroki−Heck反应物，进而合成各种取代烯烃。此外，它还是蒽荧光淬灭的有效淬灭。
溴乙酰溴它被用作有机萃取相，用于对水样、土壤和河流沉积物中的超痕量金进行离子对分散液液微萃取。
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
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signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
123.8 °F - closed cup
flash_point_c
51.0 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Heterogeneous palladium catalyst constructed with cross-linked hyperbranched poly (phenylacetylene) as polymer support: A reusable highly active ppm-level catalyst for multiple cross-coupling reactions
Dong Z and Ye Z
Applied Catalysis A: General, 489(26), 61-71 (2015)
Fluorescence quenching and external spin-orbit coupling effects
Kearvell A and Wilkinson F
Molecular Catalysis, 4(1-4), 69-81 (1968)
In situ generation of highly active dissolved palladium species from solid catalysts-a concept for the activation of aryl chlorides in the Heck reaction.
Sandra S Pröckl et al.
Angewandte Chemie (International ed. in English), 43(14), 1881-1882 (2004-04-01)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| B57702-500ML | 04061833434161 |
| B57702-18L | 04061837083945 |
| B57702-100ML | 04061833434147 |
| B57702-2L | 04061833434154 |