B78106
1-溴丙烷
99%
别名:
丙基溴
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关于此项目
线性分子式:
CH3CH2CH2Br
化学文摘社编号:
分子量:
122.99
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-445-0
Beilstein/REAXYS Number:
505936
MDL number:
Assay:
99%
Form:
liquid
InChI
1S/C3H7Br/c1-2-3-4/h2-3H2,1H3
InChI key
CYNYIHKIEHGYOZ-UHFFFAOYSA-N
SMILES string
CCCBr
vapor density
4.3 (vs air)
vapor pressure
146 mmHg ( 20 °C)
assay
99%
form
liquid
autoignition temp.
914 °F
Quality Level
bp
71 °C (lit.)
mp
−110 °C (lit.)
density
1.354 g/mL at 25 °C (lit.)
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Application
1-溴丙烷可作为各种二元混合物模型的组分，用于研究混合物特性（如粘度 和折射率等）。
可用作烷基化试剂，用于：
还可以作为反应物，用于：
可用作烷基化试剂，用于：
- 官能化硒取代的咪唑并[1,2-α]吡啶衍生物。
- 合成1,4-二羟基-2-丙氧基蒽醌衍生物。
还可以作为反应物，用于：
- 合成小檗碱-苯并咪唑衍生物。
- 通过羰基化的Barbier-Negishi与芳基碘化物偶合，合成烷基芳基酮。
signalword
Danger
Hazard Classifications
Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 3 - Ozone 1 - Repr. 1B - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3
target_organs
Central nervous system, Liver,Central nervous system, Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
76.1 °F - closed cup
flash_point_c
24.5 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Design, synthesis and biological evaluation of berberine-benzimidazole hybrids as new type of potentially DNA-targeting antimicrobial agents.
Jeyakkumar P, et al.
European Journal of Medicinal Chemistry, 122(11), 205-215 (2016)
Makoto Samukawa et al.
Archives of internal medicine, 172(16), 1257-1260 (2012-08-16)
Health hazard alerts to 1-bromopropane, an alternative to ozone layer-damaging organic solvents, have been issued by some countries. Herein, we report a new case of 1-bromopropane-induced neurotoxicity. A 43-year-old male industrial worker developed muscle weakness, pain, numbness, and gait disturbance.
Sahabudeen Sheik Mohideen et al.
Toxicology, 285(1-2), 67-71 (2011-04-30)
1-Bromopropane (1-BP) has been used as an alternative to ozone-depleting solvents. Previous studies showed that 1-BP is neurotoxic in animals and humans. In humans, exposure to 1-BP caused various neurological and neurobehavioral symptoms or signs including depressive or irritated mood.
Viscosity of pure organic liquids and binary liquid mixtures (2009)
Nickel-catalyzed C (sp2)-H selenation of imidazo [1, 2-?] pyridines with arylboronic acids or alkyl reagents using selenium powder.
Zhu J, et al.
Tetrahedron, 74(45), 6569-6576 (2018)
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