B78114
2-溴丙烷
99%
别名:
异丙基溴
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关于此项目
线性分子式:
(CH3)2CHBr
化学文摘社编号:
分子量:
122.99
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-855-1
Beilstein/REAXYS Number:
741852
MDL number:
Assay:
99%
Form:
liquid
InChI key
NAMYKGVDVNBCFQ-UHFFFAOYSA-N
InChI
1S/C3H7Br/c1-3(2)4/h3H,1-2H3
SMILES string
CC(C)Br
assay
99%
form
liquid
Quality Level
bp
59 °C (lit.)
mp
−89 °C (lit.)
density
1.31 g/mL at 25 °C (lit.)
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Application
2-溴丙烷是用于引入异丙基的通用试剂，如在合成各种 Buchwald 配体的情况下。 也可作为起始原料用于全合成 叶绿素 D、叶绿素 H、宁凝素 B 和 (±)-二向色性。
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2 - Repr. 1A - STOT RE 2 Inhalation
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
66.2 °F - closed cup
flash_point_c
19 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Efficient route to 4a-methyltetrahydrofluorenes: a total synthesis of (?)-dichroanal B via intramolecular Heck reaction.
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The Journal of Organic Chemistry, 71(7), 2896-2898 (2006)
An extremely active catalyst for the Negishi cross-coupling reaction.
Milne J E and Buchwald S L
Journal of the American Chemical Society, 126(40), 13028-13032 (2004)
The selective reaction of aryl halides with KOH: synthesis of phenols, aromatic ethers, and benzofurans.
Anderson K W, et al.
Journal of the American Chemical Society, 128(33), 10694-10695 (2006)
Total synthesis of lamellarins D, H, and R and ningalin B.
Li Q, et al.
Organic Letters, 13(2), 312-315 (2010)
G X Li et al.
The Journal of veterinary medical science, 63(4), 373-382 (2001-05-11)
2-Bromopropane (2-BP) causes testicular toxicity in humans and rats. However, the germ cell degeneration of testicular toxicity by 2-BP has not been understood. 2-BP at doses of 135, 405, and 1,355 mg/kg/day was daily injected subcutaneously into Sprague-Dawley rats for
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