B90602
叔丁基苯
99%
别名:
2-甲基-2-苯基丙烷
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关于此项目
线性分子式:
C6H5C(CH3)3
化学文摘社编号:
分子量:
134.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-632-4
Beilstein/REAXYS Number:
1421537
MDL number:
产品名称
叔丁基苯, 99%
InChI key
YTZKOQUCBOVLHL-UHFFFAOYSA-N
InChI
1S/C10H14/c1-10(2,3)9-7-5-4-6-8-9/h4-8H,1-3H3
SMILES string
CC(C)(C)c1ccccc1
vapor density
3.16 (169 °C, vs air)
vapor pressure
4.79 mmHg ( 37.7 °C)
assay
99%
form
liquid
autoignition temp.
842 °F
refractive index
n20/D 1.492 (lit.)
bp
169 °C (lit.)
mp
−58 °C (lit.)
density
0.867 g/mL at 25 °C (lit.)
Quality Level
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Application
- 气体分离应用： 叔丁基苯可用于通过共价交联合成芳香族聚酰亚胺膜，改善了其在气体分离过程中的性能，这一点对工业应用和环境管理中很关键（Lozano et al., 2022）。
- 增进拉曼散射：在纳米间隙增强拉曼散射研究中，该化合物可用作金属纳米颗粒的底物，这对分析化学很关键，为各种化合物提供了灵敏的检测方法 （Chen et al., 2021）。
- 超极化（13）C探针：它对超极化（13）C探针的合理设计很关键，使磁共振成像（MRI）技术取得重大进步，提高了诊断成像能力（Sando et al., 2018）。
General description
叔丁基苯，又称2-甲基-2-苯丙，一种芳烃，常作为合成砌块合成各种叔丁基衍生物。由于非极性特性，它是工业生产中的有效溶剂，特别适于涂料和粘合剂。
signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
116.6 °F - closed cup
flash_point_c
47 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
De-tert-butylation of substituted arenes
Saleh et al.
Tetrahedron, 54, 14157-14177 (1998)
The Orientation of Isopropyl and tert-Butyl Groups in Benzene Dialkylation
Hennion et al.
The Journal of Organic Chemistry, 17, 1102-1106 (1952)
Liquid density measurements of cumene, tert-butylbenzene, and hexadecane over wide ranges of temperature and pressure
Khasanshin et al.
Fluid Phase Equilibria, 463, 121-127 (2018)
Salvatore Fanali et al.
Journal of separation science, 29(10), 1423-1431 (2006-08-10)
Several racemic acidic compounds of pharmaceutical and environmental interest have been separated into their enantiomers by nano-liquid chromatography (nano-LC) employing a tert-butylbenzoylated tartardiamide chiral stationary phase (CHI-TBB). CHI-TBB was packed into a fused silica capillary of 100 microm id and
Clément Bonnot et al.
Journal of the American Chemical Society, 126(37), 11412-11413 (2004-09-16)
Compound 1, a cryptand-derived macropentacycle, is a flexible molecule that encompasses many conformations (symmetrical, unsymmetrical, and chiral ones) depending on the observation temperature (VT 1H NMR). Selective monoprotonation of this molecule leads to a totally unsymmetrical, rigidly chiral species in
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