C102814
2-环己烯-1-酮
≥95%
别名:
1-环己烯-3-酮, 2-环己烯酮, 3-氧环己烯, 环己烯-3-酮, 环己烯酮
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关于此项目
线性分子式:
C6H8(=O)
化学文摘社编号:
分子量:
96.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-223-5
Beilstein/REAXYS Number:
1280477
MDL number:
Assay:
≥95%
Form:
liquid
InChI
1S/C6H8O/c7-6-4-2-1-3-5-6/h2,4H,1,3,5H2
InChI key
FWFSEYBSWVRWGL-UHFFFAOYSA-N
SMILES string
O=C1CCCC=C1
vapor pressure
760 mmHg ( 168 °C)
assay
≥95%
form
liquid
refractive index
n20/D 1.488 (lit.)
bp
171-173 °C (lit.)
mp
−53 °C (lit.)
density
0.993 g/mL at 25 °C (lit.)
Quality Level
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Application
用于许多加成反应的多功能亲电试剂，包括有机铜亲核试剂的共轭加成、与烯醇硅烷的 Michael 加成以及磷鎓基硅烷化。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
132.8 °F - closed cup
flash_point_c
56 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Tetrahedron Letters, 34, 3881-3881 (1993)
Tetrahedron Asymmetry, 4, 2427-2427 (1993)
Ronaldo Mariz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(48), 14335-14347 (2010-11-16)
A family of chiral C(2)-symmetric disulfoxide ligands possessing biaryl atropisomeric backbones has been synthesized by using the Andersen methodology. Complete characterization includes X-ray crystallographic studies of all ligands and some of their rhodium complexes. Their synthesis, optical purity, electronic properties
Xingwang Wang et al.
Journal of the American Chemical Society, 130(19), 6070-6071 (2008-04-22)
A highly enantioselective epoxidation of cyclic enones with hydrogen peroxide has been developed that is catalyzed by chiral primary amine salts.
Polyssena Renzi et al.
Organic & biomolecular chemistry, 8(5), 980-983 (2010-02-19)
The multicomponent reaction between proline lithium salt, 2-cyclohexen-1-one and aliphatic aldehydes affords the 4-alkylidene-2-cyclohexen-1-ones, which are interesting fragrances, and bicyclic amino acids that bear four additional stereocenters, obtained as single stereoisomer.
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