C102814
2-环己烯-1-酮
≥95%
别名:
1-环己烯-3-酮, 2-环己烯酮, 3-氧环己烯, 环己烯-3-酮, 环己烯酮
蒸汽压
760 mmHg ( 168 °C)
方案
≥95%
表单
liquid
折射率
n20/D 1.488 (lit.)
沸点
171-173 °C (lit.)
mp
−53 °C (lit.)
密度
0.993 g/mL at 25 °C (lit.)
SMILES字符串
O=C1CCCC=C1
InChI
1S/C6H8O/c7-6-4-2-1-3-5-6/h2,4H,1,3,5H2
InChI key
FWFSEYBSWVRWGL-UHFFFAOYSA-N
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应用
用于许多加成反应的多功能亲电试剂，包括有机铜亲核试剂的共轭加成、与烯醇硅烷的 Michael 加成以及磷鎓基硅烷化。
警示用语：
Danger
危险分类
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Flam. Liq. 3
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
132.8 °F - closed cup
闪点(°C)
56 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Tetrahedron Letters, 34, 3881-3881 (1993)
Tetrahedron Asymmetry, 4, 2427-2427 (1993)
Xingwang Wang et al.
Journal of the American Chemical Society, 130(19), 6070-6071 (2008-04-22)
A highly enantioselective epoxidation of cyclic enones with hydrogen peroxide has been developed that is catalyzed by chiral primary amine salts.
Ronaldo Mariz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(48), 14335-14347 (2010-11-16)
A family of chiral C(2)-symmetric disulfoxide ligands possessing biaryl atropisomeric backbones has been synthesized by using the Andersen methodology. Complete characterization includes X-ray crystallographic studies of all ligands and some of their rhodium complexes. Their synthesis, optical purity, electronic properties
Olivia Dean et al.
Pharmacology, biochemistry, and behavior, 97(2), 293-300 (2010-09-08)
Oxidative stress has been implicated in several psychiatric illnesses, including schizophrenia. Glutathione is the brain's primary antioxidant and decreased levels of brain glutathione are reported in schizophrenia. Prepulse inhibition (PPI) is a measure of sensory gating, and PPI is reduced
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