C102814
2-环己烯-1-酮
≥95%
别名:
1-环己烯-3-酮, 2-环己烯酮, 3-氧环己烯, 环己烯-3-酮, 环己烯酮
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关于此项目
线性分子式:
C6H8(=O)
化学文摘社编号:
分子量:
96.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-223-5
Beilstein/REAXYS Number:
1280477
MDL number:
Assay:
≥95%
Form:
liquid
InChI
1S/C6H8O/c7-6-4-2-1-3-5-6/h2,4H,1,3,5H2
InChI key
FWFSEYBSWVRWGL-UHFFFAOYSA-N
SMILES string
O=C1CCCC=C1
vapor pressure
760 mmHg ( 168 °C)
assay
≥95%
form
liquid
refractive index
n20/D 1.488 (lit.)
bp
171-173 °C (lit.)
mp
−53 °C (lit.)
density
0.993 g/mL at 25 °C (lit.)
Quality Level
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Application
用于许多加成反应的多功能亲电试剂，包括有机铜亲核试剂的共轭加成、与烯醇硅烷的 Michael 加成以及磷鎓基硅烷化。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
132.8 °F - closed cup
flash_point_c
56 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Tetrahedron Letters, 34, 3881-3881 (1993)
Tetrahedron Asymmetry, 4, 2427-2427 (1993)
Xingwang Wang et al.
Journal of the American Chemical Society, 130(19), 6070-6071 (2008-04-22)
A highly enantioselective epoxidation of cyclic enones with hydrogen peroxide has been developed that is catalyzed by chiral primary amine salts.
Ronaldo Mariz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(48), 14335-14347 (2010-11-16)
A family of chiral C(2)-symmetric disulfoxide ligands possessing biaryl atropisomeric backbones has been synthesized by using the Andersen methodology. Complete characterization includes X-ray crystallographic studies of all ligands and some of their rhodium complexes. Their synthesis, optical purity, electronic properties
Olivia Dean et al.
Pharmacology, biochemistry, and behavior, 97(2), 293-300 (2010-09-08)
Oxidative stress has been implicated in several psychiatric illnesses, including schizophrenia. Glutathione is the brain's primary antioxidant and decreased levels of brain glutathione are reported in schizophrenia. Prepulse inhibition (PPI) is a measure of sensory gating, and PPI is reduced
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