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关于此项目
线性分子式:
ClCH2CN
化学文摘社编号:
分子量:
75.50
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-467-0
Beilstein/REAXYS Number:
506028
MDL number:
Assay:
99%
Form:
liquid
产品名称
氯乙腈, 99%
InChI key
RENMDAKOXSCIGH-UHFFFAOYSA-N
InChI
1S/C2H2ClN/c3-1-2-4/h1H2
SMILES string
ClCC#N
vapor density
3 (vs air)
vapor pressure
1.78 psi ( 20 °C)
assay
99%
form
liquid
refractive index
n20/D 1.422 (lit.)
bp
124-126 °C (lit.)
density
1.193 g/mL at 25 °C (lit.)
Quality Level
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Application
氯乙腈可用于:
- 合成含腈基官能化咪唑鎓盐的离子液体
- 合成氰甲基十二烷基三硫代碳酸酯,一种可逆的加成-断裂链转移(RAFT)剂。
- 作为烷基化试剂,合成三唑基噻唑衍生物,用作抗结核药。
- 作为光Meerwein加成反应的试剂,用于烯烃的氨基芳基化。
- 作为酯化剂,合成具有细胞毒性的天然产物 apicularenA。
signalword
Danger
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
129.2 °F
flash_point_c
54 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis of new S-derivatives of clubbed triazolyl thiazole as anti-Mycobacterium tuberculosis agents.
Shiradkar MR, et al.
Bioorganic & Medicinal Chemistry, 15(12), 3997-4008 (2007)
Synthesis and characterization of ionic liquids incorporating the nitrile functionality.
Zhao D, et al.
Inorganic Chemistry, 43(6), 2197-2205 (2004)
The photoredox-catalyzed Meerwein addition reaction: intermolecular amino-arylation of alkenes.
Prasad Hari D, et al.
Angewandte Chemie (International Edition in English), 53(3), 725-728 (2014)
Total synthesis of (-)-apicularen A.
Su Q and Panek JS
Journal of the American Chemical Society, 126(8), 2425-2430 (2004)
S Jacob et al.
Toxicology and industrial health, 14(4), 533-546 (1998-07-17)
Chloroacetonitrile (CAN), a drinking water disinfectant by-product, has mutagenic and carcinogenic properties. CAN is known to deplete glutathione (GSH), and previous studies reported an enhanced molecular interaction of CAN after GSH depletion in the uterine and fetal tissues of mice.
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