C2107
(1S)-(+)-10-樟脑磺酸
99%
别名:
(+)-樟脑-10-磺酸(β), (1S)-樟脑-10-磺酸
质量水平
方案
99%
表单
crystals
旋光性
[α]20/D +19.9°, c = 2 in H2O
mp
196-200 °C (dec.) (lit.)
SMILES字符串
CC1(C)[C@@H]2CC[C@@]1(CS(O)(=O)=O)C(=O)C2
InChI
1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
InChI key
MIOPJNTWMNEORI-GMSGAONNSA-N
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应用
可作为拆分剂，以及二肽偶联的催化剂。
（1S）-（+）-10-樟脑磺酸可用作合成 10-碘樟脑的原料。它还可以用作掺杂剂以在聚苯胺的导带中诱导手性。（±）-S-甲基-S-苯基亚磺酰亚胺可以用它作为手性拆分剂拆分，形成高对映体纯度的（-）-形式。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Norma J Greenfield
Nature protocols, 1(6), 2876-2890 (2007-04-05)
Circular dichroism (CD) is an excellent tool for rapid determination of the secondary structure and folding properties of proteins that have been obtained using recombinant techniques or purified from tissues. The most widely used applications of protein CD are to
Large induced optical activity in the conduction band of polyaniline doped with (1S)-(+)-10-camphorsulfonic acid.
Havinga EE, et al.
Synt. Metals, 66(1), 93-97 (1994)
Heterocycles, 31, 353-353 (1990)
Helvetica Chimica Acta, 69, 1153-1153 (1986)
An efficient resolution of (?)-S-methyl-S-phenylsulfoximine with (+)-10-camphorsulfonic acid by the method of half-quantities.
Brandt J and Gais HJ.
Tetrahedron Asymmetry, 8(6), 909-912 (1997)
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