C31104
3-氯-2-氯甲基-1-丙烯
99%
别名:
1,1-双（氯甲基）乙烯, 甲代烯丙基二氯
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关于此项目
线性分子式:
CH2=C(CH2Cl)2
化学文摘社编号:
分子量:
125.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-489-3
Beilstein/REAXYS Number:
1560178
MDL number:
Assay:
99%
Form:
liquid
InChI key
XJFZOSUFGSANIF-UHFFFAOYSA-N
InChI
1S/C4H6Cl2/c1-4(2-5)3-6/h1-3H2
SMILES string
ClCC(=C)CCl
vapor density
3.12 (vs air)
assay
99%
form
liquid
autoignition temp.
896 °F
expl. lim.
8.1 %
refractive index
n20/D 1.4753 (lit.)
bp
138 °C (lit.)
mp
−14 °C (lit.)
density
1.08 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
Application
3-氯-2-氯甲基-1-丙烯可用于合成 2,11-双（亚甲基）精胺、精胺氧化酶的抑制剂和共轭聚合物的支链侧链。它也可用于(−)-诱杀烯醇全合成过程中的分子间[2+2]光环加成反应。
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
96.8 °F
flash_point_c
36 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Enantioselective Intermolecular [2+ 2] Photocycloaddition Reaction of Cyclic Enones and Its Application in a Synthesis of (−)-Grandisol.
Poplata S and Bach T
Journal of the American Chemical Society, 140(9), 3228-3231 (2018)
Diketopyrrolopyrrole?based Conjugated Polymers Bearing Branched Oligo (Ethylene Glycol) Side Chains for Photovoltaic Devices.
Chen X, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 128(35), 10532-10536 (2016)
Synthesis of well-defined three-and four-armed cage-shaped polymers via ?topological conversion? from trefoil-and quatrefoil-shaped polymers.
Satoh Y, et al.
Macromolecules, 50(1), 97-106 (2016)
Synthesis of 2, 11-bis (methylidene) spermine, a new inhibitor of spermine oxidase.
Grigorenko N A, et al.
Russian Journal of Bioorganic Chemistry, 42(4), 423-427 (2016)
Matthew K McBride et al.
Science advances, 4(8), eaat4634-eaat4634 (2018-08-29)
Liquid crystalline (LC) elastomers (LCEs) enable large-scale reversible shape changes in polymeric materials; however, they require intensive, irreversible programming approaches in order to facilitate controllable actuation. We have implemented photoinduced dynamic covalent chemistry (DCC) that chemically anneals the LCE toward
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