C86006
巴豆醇，顺式和反式混合物
96%
别名:
2-丁烯-1-醇
质量水平
方案
96%
表单
liquid
折射率
n20/D 1.427 (lit.)
沸点
121-122 °C (lit.)
密度
0.845 g/mL at 25 °C (lit.)
SMILES字符串
C\C=C\CO
InChI
1S/C4H8O/c1-2-3-4-5/h2-3,5H,4H2,1H3/b3-2+
InChI key
WCASXYBKJHWFMY-NSCUHMNNSA-N
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应用
巴豆醇可用作合成 14-氮杂喜树碱和 10,11-亚甲基二氧基-14-氮杂喜树碱等抗肿瘤药的起始原料。它也可以用作盘皮海绵内酯全合成中的前体。
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
93.2 °F - closed cup
闪点(°C)
34 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis of optically active β-alkyl aspartate via [3, 3] sigmatropic rearrangement of α-acyloxytrialkylsilane.
Sakaguchi K, et al.
Tetrahedron Letters, 45(30), 5869-5872 (2004)
Total synthesis of discodermolide: optimization of the effective synthetic route.
de Lemos E, et al.
Chemistry?A European Journal , 14(35), 11092-11112 (2008)
Synthesis of 14-azacamptothecin, a water-soluble topoisomerase I poison.
Rahier N J, et al.
Organic Letters, 7(5), 835-837 (2005)
Frank R Fontaine et al.
Chemical research in toxicology, 15(8), 1051-1058 (2002-08-20)
Recent confirmation that the toxic unsaturated aldehyde crotonaldehyde (CA) contributes to protein damage during lipid peroxidation confers interest on the molecular actions of this substance. However, since a plethora of structurally related aldehydes form during membrane oxidation, clarifying the toxicological
Darby R Schmidt et al.
Organic letters, 5(19), 3535-3537 (2003-09-12)
[structure: see text] A synthesis of the C(15)-C(30) fragment of Dolabelides A and B has been achieved. The recently developed asymmetric silane alcoholysis and tandem silylformylation-crotylsilylation reactions were used as the key steps to establish the C(23)-C(27) 1,5-syn-diol. In addition
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