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Merck
CN

CF0002

1-Fluoro-3,3-dimethylbenziodoxole

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关于此项目

线性分子式:
C9H10FIO
化学文摘社编号:
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
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SMILES string

[I]1(OC(c2c1cccc2)(C)C)F

InChI

1S/C9H10FIO/c1-9(2)7-5-3-4-6-8(7)11(10)12-9/h3-6H,1-2H3

InChI key

FISITPXJYDTLHI-UHFFFAOYSA-N

form

solid

reaction suitability

reaction type: C-C Bond Formation

Application

1-Fluoro-3,3-dimethylbenziodoxole is a crystalline, off-white solid which can be handled under air for extended periods without noticeable hydrolytic decomposition. In the presence of excess fluoride ions (provided by triethylamine-hydrogen fluoride complexes), it can effectively function as an electrophilic fluorination reagent for easily enolizable diketo substrates, or it can engage in silver catalyzed difluorination of styrenes.

Automate your fluorination reactions with Synple Automated Synthesis Platform (SYNPLE-SC002)

Legal Information

Product of CF Plus Chemicals.

pictograms

Flame over circle

signalword

Danger

hcodes

pcodes

Hazard Classifications

Ox. Sol. 2

存储类别

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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分析证书(COA)

Lot/Batch Number

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Fluoroalkylation toolbox expands with various reagents for late-stage fluoroalkylation in organic synthesis and medicinal chemistry.

目前的氟烷基化工具包括Togni试剂、高价碘全氟烷基化试剂、氟烷基溴化物、硅烷类和羧酸盐类以及用于后期氟烷基化的磺酰氟类。

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