D12600
3,4-二氨基苯甲酸
97%
别名:
4-Carboxy-o-phenylenediamine
方案
97%
表单
powder
反应适用性
reaction type: solution phase peptide synthesis
mp
208-210 °C (dec.) (lit.)
应用
peptide synthesis
SMILES字符串
Nc1ccc(cc1N)C(O)=O
InChI
1S/C7H8N2O2/c8-5-2-1-4(7(10)11)3-6(5)9/h1-3H,8-9H2,(H,10,11)
InChI key
HEMGYNNCNNODNX-UHFFFAOYSA-N
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应用
3,4-二氨基苯甲酸可用于制备：
- 席夫碱衍生物（通过与取代醛及其相应的金属络合物反应生成）
- 聚（2，5-苯并咪唑）(ABPBI) 聚合物（通过与甲磺酸和P2O5反应生成）
- 适用于H2O裂解反应的Pt基席夫碱络合物。
3,4-二氨基苯甲酸通过环缩合反应形成，如喹喔啉和 苯并咪唑。
储存分类代码
11 - Combustible Solids
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
New platinum and ruthenium Schiff base complexes for water splitting reactions
Wang C, et al.
Dalton Transactions, 44(32), 14483-14493 (2015)
N Sundaraganesan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 70(2), 376-383 (2007-12-28)
The Fourier Transform Raman and Fourier Transform infrared spectra of 3,4-diaminobenzoic acid (3,4-DABA) were recorded in the solid phase. Geometry optimizations were done without any constraint and harmonic-vibrational wave numbers and several thermodynamic parameters were calculated for the minimum energy
Osmar Calderon Sanchez et al.
Nuclear medicine and biology, 33(3), 381-390 (2006-04-25)
Preformed (99m)Tc chelates with an activated ester function are useful for the gentle labeling of proteins (precomplexation route). In this context, new heterobifunctional ligands derived from 2,3,5,6-tetrafluorophenyl (TFP) 3,4-diamino-benzoates (OC1, OC3, OC4) were synthesized. Their corresponding (99m)Tc-complexation and protein-conjugation characteristics
Santosh K Mahto et al.
Chembiochem : a European journal of chemical biology, 12(16), 2488-2494 (2011-09-13)
C-terminal peptide thioesters are an essential component of the native chemical ligation approach for the preparation of fully or semisynthetic proteins. However, the efficient generation of C-terminal thioesters by Fmoc solid-phase peptide synthesis remains a challenge. The recent N-acylurea approach
Synthesis of poly (2, 5-benzimidazole) for use as a fuel-cell membrane
Kim H, et al.
Macromolecular Rapid Communications, 25(8), 894-897 (2004)
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