D12600
3,4-二氨基苯甲酸
97%
别名:
4-Carboxy-o-phenylenediamine
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关于此项目
线性分子式:
(H2N)2C6H3CO2H
化学文摘社编号:
分子量:
152.15
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-577-2
Beilstein/REAXYS Number:
775892
MDL number:
产品名称
3,4-二氨基苯甲酸, 97%
InChI key
HEMGYNNCNNODNX-UHFFFAOYSA-N
InChI
1S/C7H8N2O2/c8-5-2-1-4(7(10)11)3-6(5)9/h1-3H,8-9H2,(H,10,11)
SMILES string
Nc1ccc(cc1N)C(O)=O
assay
97%
form
powder
reaction suitability
reaction type: solution phase peptide synthesis
mp
208-210 °C (dec.) (lit.)
application(s)
peptide synthesis
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Application
3,4-二氨基苯甲酸可用于制备：
- 席夫碱衍生物（通过与取代醛及其相应的金属络合物反应生成）
- 聚（2，5-苯并咪唑）(ABPBI) 聚合物（通过与甲磺酸和P2O5反应生成）
- 适用于H2O裂解反应的Pt基席夫碱络合物。
3,4-二氨基苯甲酸通过环缩合反应形成，如喹喔啉和 苯并咪唑。
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
New platinum and ruthenium Schiff base complexes for water splitting reactions
Wang C, et al.
Dalton Transactions, 44(32), 14483-14493 (2015)
N Sundaraganesan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 70(2), 376-383 (2007-12-28)
The Fourier Transform Raman and Fourier Transform infrared spectra of 3,4-diaminobenzoic acid (3,4-DABA) were recorded in the solid phase. Geometry optimizations were done without any constraint and harmonic-vibrational wave numbers and several thermodynamic parameters were calculated for the minimum energy
Tetrahedron, 49, 9823-9823 (1993)
New 3, 4-diaminobenzoic acid Schiff base compounds and their complexes: Synthesis, characterization and thermodynamics
Mohammadi K, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 122, 179-185 (2014)
L A Cooper et al.
Antonie van Leeuwenhoek, 50(1), 53-62 (1984-01-01)
The effect of various compounds on growth, melanin biosynthesis and cell differentiation was studied in a hyaline (SH25) and a pigmented (SH25B) strain of Microdochium bolleyi. Dark pigment production by the hyaline strain was induced by the presence of DOPA
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