D129208
甲苯-3,4-二硫酚
technical grade, 90%
别名:
3,4-二巯基甲苯, 3,4-甲苯二硫醇, 4-甲基邻二苯硫酚
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线性分子式:
CH3C6H3(SH)2
化学文摘社编号:
分子量:
156.27
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-828-3
Beilstein/REAXYS Number:
1635270
MDL number:
产品名称
甲苯-3,4-二硫酚, technical grade, 90%
InChI
1S/C7H8S2/c1-5-2-3-6(8)7(9)4-5/h2-4,8-9H,1H3
InChI key
NIAAGQAEVGMHPM-UHFFFAOYSA-N
SMILES string
Cc1ccc(S)c(S)c1
grade
technical grade
assay
90%
form
powder
bp
135-137 °C/17 mmHg (lit.)
mp
30-33 °C (lit.)
density
1.179 g/mL at 25 °C (lit.)
storage temp.
−20°C
Quality Level
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Application
在双核二硫酚金(I) 配合物研究中用于生成相应的二硫酚配体。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Inorganic Chemistry, 32, 1749-1749 (1993)
Carsten Milsmann et al.
Inorganic chemistry, 48(20), 9754-9766 (2009-09-23)
The reaction of [Ru(III)(cyclam)Cl(2)]Cl with 2 equiv of sodium N,N-diethyldithiocarbamate in methanol afforded [Ru(II)(cyclam)(Et(2)dtc)](BPh(4)) (1(BPh(4))). The same reaction with only 1 equiv of toluene-3,4-dithiol and a base yielded [Ru(cyclam)(tdt)](PF(6)) (2(PF(6))) which was oxidized by 1 equiv of ferrocenium hexafluorophosphate generating
Ulf Ryde et al.
Journal of the American Chemical Society, 132(13), 4512-4513 (2010-03-17)
The active site of the [FeFe] hydrogenases contains two Fe ions bound to one Cys ligand, three CO molecules, two CN(-) ions, and a dithiolate ligand. The nature of the last of these has been much discussed, and it has
A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene.
Gaël Ung et al.
Angewandte Chemie (International ed. in English), 50(18), 4215-4218 (2011-04-08)
Weidong Zhou et al.
Organic letters, 12(18), 4078-4081 (2010-08-18)
A macrocycle and a rotaxane were constructed by virtue of the thiol-yne click reaction under the irradiation of light in high yield, which can proceed at ambient temperature and humidity under an air atmosphere. Two disulfide macrocycles were synthesized through
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