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D129208

甲苯-3,4-二硫酚

Name: 甲苯-3,4-二硫酚
Brand: ALDRICH

technical grade, 90%

别名:

3,4-二巯基甲苯, 3,4-甲苯二硫醇, 4-甲基邻二苯硫酚

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关于此项目

线性分子式:

CH₃C₆H₃(SH)₂

化学文摘社编号:

496-74-2

分子量:

156.27

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24893400

EC Number:

207-828-3

Beilstein/REAXYS Number:

1635270

MDL number:

MFCD00004844

Assay:

90%

Form:

powder

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属性

grade

technical grade

Quality Level

200

assay

90%

form

powder

bp

135-137 °C/17 mmHg (lit.)

mp

30-33 °C (lit.)

density

1.179 g/mL at 25 °C (lit.)

storage temp.

−20°C

SMILES string

Cc1ccc(S)c(S)c1

InChI

1S/C7H8S2/c1-5-2-3-6(8)7(9)4-5/h2-4,8-9H,1H3

InChI key

NIAAGQAEVGMHPM-UHFFFAOYSA-N

说明

Application

在双核二硫酚金(I) 配合物研究中用于生成相应的二硫酚配体。

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存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Inorganic Chemistry, 32, 1749-1749 (1993)

Quantum refinement of [FeFe] hydrogenase indicates a dithiomethylamine ligand.

Ulf Ryde et al.

Journal of the American Chemical Society, 132(13), 4512-4513 (2010-03-17)

The active site of the [FeFe] hydrogenases contains two Fe ions bound to one Cys ligand, three CO molecules, two CN(-) ions, and a dithiolate ligand. The nature of the last of these has been much discussed, and it has

Electronic structures of [Ru(II)(cyclam)(Et(2)dtc)](+), [Ru(cyclam)(tdt)](+), and [Ru(cyclam)(tdt)](2+): an X-ray absorption spectroscopic and computational study (tdt = toluene-3,4-dithiolate; Et(2)dtc = N,N-diethyldithiocarbamate(1-)).

Carsten Milsmann et al.

Inorganic chemistry, 48(20), 9754-9766 (2009-09-23)

The reaction of [Ru(III)(cyclam)Cl(2)]Cl with 2 equiv of sodium N,N-diethyldithiocarbamate in methanol afforded [Ru(II)(cyclam)(Et(2)dtc)](BPh(4)) (1(BPh(4))). The same reaction with only 1 equiv of toluene-3,4-dithiol and a base yielded [Ru(cyclam)(tdt)](PF(6)) (2(PF(6))) which was oxidized by 1 equiv of ferrocenium hexafluorophosphate generating

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全球贸易项目编号

货号	GTIN
D129208-1ML	04061837252860
D129208-5ML	04061837252877