D206008
反,反-1,4-二苯基-1,3-丁二烯
98%
别名:
β,β′-二苯乙烯基, DPB
质量水平
方案
98%
表单
crystals
沸点
350 °C (lit.)
mp
150-152 °C (lit.)
SMILES字符串
c1ccc(cc1)\C=C\C=C\c2ccccc2
InChI
1S/C16H14/c1-3-9-15(10-4-1)13-7-8-14-16-11-5-2-6-12-16/h1-14H/b13-7+,14-8+
InChI key
JFLKFZNIIQFQBS-FNCQTZNRSA-N
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应用
反,反-1,4-二苯基-1,3-丁二烯可用作合成以下物质的反应物：
它还可作为配体，与银(I)盐反应制备银(I)配位聚合物。
- 通过与硫化钾和DMSO的氧化反应合成的2,5-二苯基噻吩。
- 在 N2H4存在的情况下通过与糠醛进行镍催化加氢苄基化反应合成的2-[(3E)-4-苯基-2-(苯甲基)-3-丁烯-1-基]呋喃。
它还可作为配体，与银(I)盐反应制备银(I)配位聚合物。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
David P Burgner et al.
PloS one, 10(5), e0125342-e0125342 (2015-05-06)
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Syntheses and structural studies on silver (I) coordination polymers with trans, trans-1, 4-dipenyl-1, 3-butadiene
Zhong JC, et al.
Inorganica chimica acta, 342, 202-208 (2003)
Liang Chen et al.
Organic letters, 20(23), 7392-7395 (2018-11-22)
A novel, atom economical, and transition-metal-free strategy for the synthesis of thiophenes from substituted buta-1-enes with potassium sulfide has been presented. The reaction achieves double C-S bond formations via cleavage of multiple C-H bonds and provides an efficient approach to
Nickel-catalyzed regioselective hydrobenzylation of 1, 3-dienes with hydrazones
Lv Leiyang, et al.
ACS Catalysis, 9(10), 9199-9205 (2019)
Vikram Agarwal et al.
eLife, 4 (2015-08-13)
MicroRNA targets are often recognized through pairing between the miRNA seed region and complementary sites within target mRNAs, but not all of these canonical sites are equally effective, and both computational and in vivo UV-crosslinking approaches suggest that many mRNAs
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