D216402
2,2′-二吡啶胺
98%
别名:
二吡啶胺
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关于此项目
经验公式（希尔记法）:
C10H9N3
化学文摘社编号:
分子量:
171.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-864-3
Beilstein/REAXYS Number:
127131
MDL number:
产品名称
2,2′-二吡啶胺, 98%
InChI key
HMMPCBAWTWYFLR-UHFFFAOYSA-N
InChI
1S/C10H9N3/c1-3-7-11-9(5-1)13-10-6-2-4-8-12-10/h1-8H,(H,11,12,13)
SMILES string
N(c1ccccn1)c2ccccn2
assay
98%
form
solid
bp
222 °C/50 mmHg (lit.)
mp
90-92 °C (lit.)
Quality Level
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Application
2,2′-二吡啶胺 (bipyam) 可用于：
- 作为二齿N-配位体用于合成各种金属络合物。
- 用于合成钯-聚氧钒酸盐，这是一种用于苯甲基烃氧化的多相催化剂。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Heather R Lucas et al.
Journal of the American Chemical Society, 132(37), 12927-12940 (2010-08-24)
The kinetics, thermodynamics, and coordination dynamics are reported for O(2) and CO 1:1 binding to a series of pseudo-tetradentate ligand-copper(I) complexes ((D)LCu(I)) to give Cu(I)/O(2) and Cu(I)/CO product species. Members of the (D)LCu(I) series possess an identical tridentate core structure
Runyu Tan et al.
Inorganic chemistry, 51(13), 7039-7049 (2012-06-13)
A novel multidentate ligand with 2,2'-dipyridylamine functionalities, 1,8-bis[4-(2,2'-dipyridylamino)phenylacetylenyl]anthracene (1), has been synthesized through a double Sonogashira coupling reaction and characterized by NMR spectroscopic, elemental, and X-ray diffraction analyses. Compound 1 can bind to either one metal center as a tetradentate
John J Allen et al.
Dalton transactions (Cambridge, England : 2003), (5)(5), 878-890 (2009-01-22)
Complexes of the type [Cu(H-dpa)(olefin)]BF4 for ethylene (1), propylene (2), 1-butene (3), 1-hexene (4), 1-octene (5), cis-2-octene (6), trans-2-octene (7), cis-3-octene (8), trans-3-octene (9), 2-norbornylene (10), 1,5-cyclooctadiene (11), styrene (12), cis-stilbene (13), trans-stilbene (14), and Ph2C=CH2 (15) have been prepared
Y Kobayashi et al.
Xenobiotica; the fate of foreign compounds in biological systems, 30(7), 683-692 (2000-08-30)
1. The effect of 2,2'-dipyridyl ketone and 2,2'-dipyridyl amine on the induction of hepatic microsomal cytochrome P450 (P450) and heme oxygenase was compared, and their effects on five different P450 isoforms (P4501A1, 3A2, 2B1, 2E1 and 2C11) in rat were
Chao Tu et al.
Inorganic chemistry, 42(19), 5795-5797 (2003-09-16)
A novel hexadentate ligand, N,N,N',N',N",N"-hexa(2-pyridyl)-1,3,5-tris(aminomethyl)benzene (L), was designed and synthesized. The X-ray structure analysis reveals that the three dipyridylamine (DPA) groups of L are almost perpendicular to the central trimethylenebenzene, and two of them are spacially close to each other
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