D44952
二丁胺
≥98%
别名:
二丁基胺
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关于此项目
线性分子式:
(CH3CH2CH2CH2)2NH
化学文摘社编号:
分子量:
129.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-921-8
Beilstein/REAXYS Number:
506001
MDL number:
Assay:
≥98%
Bp:
159 °C (lit.)
Vapor pressure:
1.9 mmHg ( 20 °C)
vapor density
4.46 (vs air)
Quality Level
vapor pressure
1.9 mmHg ( 20 °C)
assay
≥98%
form
liquid
autoignition temp.
594 °F
expl. lim.
10 %
refractive index
n20/D 1.417 (lit.)
pH
11.1 (20 °C, 1 g/L)
bp
159 °C (lit.)
mp
−62 °C (lit.)
density
0.767 g/mL at 25 °C (lit.)
SMILES string
CCCCNCCCC
InChI
1S/C8H19N/c1-3-5-7-9-8-6-4-2/h9H,3-8H2,1-2H3
InChI key
JQVDAXLFBXTEQA-UHFFFAOYSA-N
Application
- 二丁基胺广泛用于钯催化与芳基卤化物交叉偶联合成芳基胺，通称为 Buchwald–Hartwig 胺化。
- 可用于氧杂酮介导的 2-氨基苯甲酰胺和 1，2-二氨基苯的环合反应，分别合成 2，3-二氢喹唑啉-4 (1 H )-酮和 1 H -苯并咪唑。
- 也可用于一锅法多组分反应，合成四取代和五取代的多官能团二氢吡咯。
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signalword
Danger
存储类别
3 - Flammable liquids
flash_point_f
104.9 °F - closed cup
flash_point_c
40.5 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
法规信息
危险化学品
此项目有
Oxone-mediated annulation of 2-aminobenzamides and 1, 2-diaminobenzenes with sec-amines via imine-N-oxides: new syntheses of 2, 3-dihydroquinazolin-4 (1 H)-ones and 1 H-benzimidazoles.
Sriramoju V, et al.
New. J. Chem., 42(5), 3188-3191 (2018)
Simple, efficient catalyst system for the palladium-catalyzed amination of aryl chlorides, bromides, and triflates.
Wolfe J P, et al.
The Journal of Organic Chemistry, 65(4), 1158-1174 (2000)
Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides.
Kuwano R, et al.
The Journal of Organic Chemistry, 67(18), 6479-6486 (2002)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| D44952-500G | 04061833564455 |
| D44952-1.5KG | 04061837512247 |