D45800
3,5-二叔丁基儿茶酚
98%
别名:
3,5-二叔丁基-1,2-二羟基苯, 3,5-二叔丁基-1,2-苯二醇, 3,5-二叔丁基邻氢醌, 3,5-二叔丁基邻苯二酚, 3,5-双(1,1-二甲基乙基)-1,2-苯二醇, 4,6-二叔丁基-1,2-苯二醇, 4,6-二叔丁基邻苯二酚
方案
98%
表单
crystals
mp
95-100 °C (lit.)
SMILES字符串
CC(C)(C)c1cc(O)c(O)c(c1)C(C)(C)C
InChI
1S/C14H22O2/c1-13(2,3)9-7-10(14(4,5)6)12(16)11(15)8-9/h7-8,15-16H,1-6H3
InChI key
PJZLSMMERMMQBJ-UHFFFAOYSA-N
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应用
3,5-二-叔丁基儿茶酚可用作：
- 通过催化氧化制备3,5-二-叔-丁基醌的反应物。
- 苯乙烯和丁二烯等单体生产中的聚合抑制剂。
- 以L-脯氨酸为催化剂通过不对称亚硝基羟醛缩反应合成对映选择性 1,2-恶嗪烷和异恶唑烷的添加剂。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Apurba Biswas et al.
Inorganic chemistry, 51(19), 10111-10121 (2012-09-12)
A diphenoxido-bridged dinuclear copper(II) complex, [Cu(2)L(2)(ClO(4))(2)] (1), has been synthesized using a tridentate reduced Schiff base ligand, 2-[[2-(diethylamino)ethylamino]methyl]phenol (HL). The addition of triethylamine to the methanolic solution of this complex produced a novel triple bridged (double phenoxido and single hydroxido)
Karin Born et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 12(1), 36-48 (2006-09-12)
A mechanism for the oxidation of 3,5-di-tert-butylcatechol (dtbc) with dioxygen to the corresponding quinone (dtbq), catalyzed by bispidine-dicopper complexes (bispidines are various mono- and dinucleating derivatives of 3,7-diazabicyclo[3.3.1]nonane with bis-tertiary-amine-bispyridyl or bis-tertiary-amine-trispyridyl donor sets), is proposed on the basis of
Cindy-Xing Yin et al.
Journal of the American Chemical Society, 127(40), 13988-13996 (2005-10-06)
Recently we showed that V-containing polyoxometalates such as (n-Bu4N)7SiW9V3O40 or (n-Bu4N)9P2W15V3O62, as well as eight other V-containing precatalysts tested, evolve to high-activity, long catalytic lifetime (> or = 30,000-100,000 total turnovers) 3,5-di-tert-butylcatechol (DTBC) dioxygenases in which Pierpont's complex [VO(DBSQ)(DTBC)]2 is
Edgar Mijangos et al.
Dalton transactions (Cambridge, England : 2003), (14)(14), 1857-1863 (2008-03-29)
A potentially dodecadentate N8O4-donor ligand obtained from 2,2'-biimidazole and l-valine and its tetranuclear Cu(ii) complexes in different degrees of protonation were characterized by chemical and spectroscopic methods. The extensive solution studies performed reveal that the rise in pH media leads
María Rosa Mendoza-Quijano et al.
Dalton transactions (Cambridge, England : 2003), 41(16), 4985-4997 (2012-03-14)
The catecholase activity of two dinuclear Cu(II) complexes with distant metal centers is discussed together with solid state and solution studies. The crystal structure for one of them, [Cu(2)(diep)(H(2)O)(4)](ClO(4))(4)·2H(2)O, is described, showing the two copper ions are 7.457 Å apart
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