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Merck
CN

D7148

3,4-二氨基吡啶

≥98%

别名:

3,4-DAP, 4,5-二氨基吡啶, DAP, 二氨吡啶, 吡啶-4,5-二胺

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关于此项目

经验公式（希尔记法）:
C5H7N3
化学文摘社编号:
54-96-6
分子量:
109.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
57654120
EC Number:
200-220-9
Beilstein/REAXYS Number:
110232
MDL number:
MFCD00006401

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产品名称

3,4-二氨基吡啶, ≥98%

InChI key

OYTKINVCDFNREN-UHFFFAOYSA-N

InChI

1S/C5H7N3/c6-4-1-2-8-3-5(4)7/h1-3H,7H2,(H2,6,8)

SMILES string

Nc1ccncc1N

assay

≥98%

form

powder

mp

216-218 °C (lit.)

Quality Level

100

Gene Information

human ... KCNA1(3736), KCNA10(3744), KCNA2(3737), KCNA3(3738), KCNA4(3739), KCNA5(3741), KCNA6(3742), KCNA7(3743), KCNB1(3745), KCNB2(9312), KCNC1(3746), KCNC2(3747), KCNC3(3748), KCNC4(3749), KCND1(3750), KCND2(3751), KCND3(3752), KCNF1(3754), KCNG1(3755), KCNG2(26251), KCNG3(170850), KCNG4(93107), KCNH1(3756), KCNH2(3757), KCNH3(23416), KCNH4(23415), KCNH5(27133), KCNH6(81033), KCNH7(90134), KCNH8(131096), KCNQ1(3784), KCNQ2(3785), KCNQ3(3786), KCNQ4(9132), KCNQ5(56479), KCNS1(3787), KCNS2(3788), KCNS3(3790), KCNV1(27012), KCNV2(169522)

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相关类别

Application

3,4-二氨基吡啶可用作制备以下物质的杂环构建单元：      
  • 咪唑并[4,5-c]吡啶，一种用于制备 CP-885316 的重要支架。     
  • 9-氮杂双环烷衍生物，其被用作酰化和氮杂-莫里塔-贝利斯-希尔曼反应的有效有机催化剂。      
  • 2-苯基吡啶并[3,4-b]吡嗪，通过在苯/乙酸溶剂中与 α-甲基亚磺酰基苯乙酮缩合反应而生成。

General description

3,4-二氨基吡啶，又称阿米吡呖(Amifampridine)，一种杂环化合物，常用作合成砌块制备咪唑并[4,5-c]吡啶和Co(III)席夫碱络合物。

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Eye Irrit. 2

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCL5276
BCCH4243
BCCD6340
BCCB1729
BCBZ9128

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Raman Tandon et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(20), 6435-6442 (2013-03-19)
New heterocyclic derivatives of 9-azajulolidine have been synthesized and characterized with respect to their nucleophilicity and Lewis basicity. The Lewis basicity of these bases as quantified through their theoretically calculated methyl-cation affinities correlate well with the experimentally measured reaction rates
Monika Cecilija Žužek et al.
Toxicology letters, 281, 95-101 (2017-09-25)
The effects of natural polymeric alkylpyridinium salt (nPoly-3-APS), a potent acetylcholinesterase inhibitor isolated from the marine sponge Reniera sarai, were studied on isolated mouse phrenic nerve-hemidiaphragm muscle preparations using electrophysiological approaches. nPoly-3-APS inhibited nerve-evoked isometric muscle twitch and tetanic contraction
Regioselective Synthesis of an Imidazo [4, 5-c] pyridine through Selective Acylation of 3, 4-Diaminopyridine: Synthesis of CP-885,316
Caron S, et al.
Organic Process Research & Development, 10(2), 257-261 (2006)
Synthesis of 2-Arylpyrido [3, 4-b] pyrazine Derivatives through Condensation of 3, 4-Diaminopyridine with ?-Keto Sulfoxides
Kano S and Yuasa Y
Journal of Heterocyclic Chemistry, 20(3), 769-770 (1983)
Xuejing Song et al.
Materials (Basel, Switzerland), 11(10) (2018-10-27)
Pyrazine derivatives quinoxaline and pyridopyrazine were selected as the acceptors, and benzocarbazole was used as the donor to synthesize four different D⁻A⁻D compounds. The results showed that 2,3-bis(decyloxy)pyridine[3,4-b]pyrazine (DPP) exhibited stronger electron-withdrawing ability than that of 2,3-bis(decyloxy)quinoxaline (DPx), because DPP
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