D7600
双丙酮葡萄糖
98%
别名:
1,2,5,6-二异亚丙基-D-葡萄糖, 乙酰丙酮-D-葡萄糖, 二丙酮-D-葡萄糖
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关于此项目
经验公式（希尔记法）:
C12H20O6
化学文摘社编号:
分子量:
260.28
UNSPSC Code:
12352201
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-486-0
Beilstein/REAXYS Number:
84386
MDL number:
Quality Segment
assay
98%
form
powder
optical activity
[α]20/D −18°, c = 1% in H2O
mp
109-113 °C (lit.)
SMILES string
[H][C@@]1(O[C@H]2O[C@@H](O[C@@H]2[C@H]1O)C(Cl)(Cl)Cl)[C@H]3COC(C)(C)O3
InChI
1S/C12H20O6/c1-11(2)14-5-6(16-11)8-7(13)9-10(15-8)18-12(3,4)17-9/h6-10,13H,5H2,1-4H3/t6-,7+,8-,9-,10-/m1/s1
InChI key
KEJGAYKWRDILTF-JDDHQFAOSA-N
Application
1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose can be used as a starting material to prepare:
- Biologically active L-acovenose, 6-deoxy-L-idose and, carbanucleoside enantiomers.
- Vinyl ether-based chiral carbohydrate synthon by reacting with acetylene using superbase catalytic systems.
- Fluoro-thiofuranosyl nucleosides of biological importance.
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存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)