D77001
己二腈
99%
别名:
1,6-hexanedinitrile, ADN, 1，4-二氰基丁烷
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线性分子式:
NC(CH2)4CN
化学文摘社编号:
分子量:
108.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-896-3
Beilstein/REAXYS Number:
1740005
MDL number:
Assay:
99%
Form:
liquid
InChI key
BTGRAWJCKBQKAO-UHFFFAOYSA-N
InChI
1S/C6H8N2/c7-5-3-1-2-4-6-8/h1-4H2
SMILES string
N#CCCCCC#N
vapor density
3.7 (vs air)
vapor pressure
0.01 mmHg ( 40 °C)
assay
99%
form
liquid
autoignition temp.
1022 °F
expl. lim.
4.99 %
Quality Level
bp
295 °C (lit.)
mp
1-3 °C (lit.)
density
0.951 g/mL at 25 °C (lit.)
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Application
己二腈是制造尼龙-6,6的关键前体。 它可以进行催化氢化以形成六亚甲基二胺（HMD）。 由于其高阳极和热稳定性，ADN非常有潜力作为高压锂电池中电解质溶液的溶剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 1
flash_point_f
325.4 °F - closed cup
flash_point_c
163 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Raghuraj Rao et al.
Analytica chimica acta, 599(1), 24-35 (2007-09-04)
Multivariate calibration problems often involve the identification of a meaningful subset of variables, from a vast number of variables for better prediction of output variables. A new graph theoretic method based on partial correlations (variable interaction network-VIN) is proposed. Many
O L Dashiell et al.
Journal of applied toxicology : JAT, 4(6), 320-325 (1984-12-01)
Nine chemicals, with a range from extremely to slightly toxic, were used to measure the oral LD50 in both fasted (24-h) and non-fasted rats. Each chemical was tested as a solution or suspension in corn oil, responses within 14 days
Inhalation toxicity of adiponitrile in rats.
L W Smith et al.
Toxicology and applied pharmacology, 65(2), 257-263 (1982-09-15)
F R Johannsen et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 7(1), 33-40 (1986-07-01)
Acetonitrile (ACN), adiponitrile (ADN), and propionitrile (PN), were evaluated for embryotoxic and teratogenic potential in rats. Mated Sprague-Dawley rats were administered one of the three nitriles by gavage on gestation Days 6-19, inclusive. Daily dosage levels (mg/kg body wt) were:
Jian-Jun Dai et al.
ChemSusChem, 5(4), 617-620 (2012-03-24)
Current affairs: Adiponitrile, used to produce nylon 6.6, is prepared from the renewable compound glutamic acid by an electrochemical route, involving electro-oxidative decarboxylation and Kolbe coupling reactions. The new route is an example of the use of glutamic acid as
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