D77001
己二腈
99%
别名:
1,6-hexanedinitrile, ADN, 1，4-二氰基丁烷
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线性分子式:
NC(CH2)4CN
化学文摘社编号:
分子量:
108.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-896-3
Beilstein/REAXYS Number:
1740005
MDL number:
产品名称
己二腈, 99%
InChI key
BTGRAWJCKBQKAO-UHFFFAOYSA-N
InChI
1S/C6H8N2/c7-5-3-1-2-4-6-8/h1-4H2
SMILES string
N#CCCCCC#N
vapor density
3.7 (vs air)
vapor pressure
0.01 mmHg ( 40 °C)
assay
99%
form
liquid
autoignition temp.
1022 °F
expl. lim.
4.99 %
refractive index
n20/D 1.438 (lit.)
bp
295 °C (lit.)
mp
1-3 °C (lit.)
density
0.951 g/mL at 25 °C (lit.)
Quality Level
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Application
己二腈是制造尼龙-6,6的关键前体。 它可以进行催化氢化以形成六亚甲基二胺（HMD）。 由于其高阳极和热稳定性，ADN非常有潜力作为高压锂电池中电解质溶液的溶剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 1
flash_point_f
325.4 °F - closed cup
flash_point_c
163 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
J L Moreau et al.
Journal of chromatography. B, Biomedical applications, 656(1), 197-202 (1994-06-03)
A procedure for the assay of nitrile hydratase and amidase activity by high-performance liquid chromatography is described. The method can be used to assay the intermediate compounds resulting from the hydrolysis of adiponitrile into adipic acid, and to determine the
Gerald L Kennedy
Drug and chemical toxicology, 27(2), 123-131 (2004-06-17)
Adiponitrile (ADN) has moderate acute toxicity with an oral LD50 in rats of 100 to 500 mg/kg and a 4-hr LC50 in rats of 1.71 mg/L (vapor plus aerosol). ADN produced slight eye but no skin irritation in rabbits. Repeated
J L Moreau et al.
The Analyst, 116(12), 1381-1383 (1991-12-01)
A procedure for the assay of nitrile hydratase and amidase activities by high-performance liquid chromatography is described. The method can be used to assay the intermediate compounds resulting from the hydrolysis of adiponitrile to adipic acid, and to determine the
The catalytic hydrogenation of adiponitrile to hexamethylenediamine over a rhodium/alumina catalyst in a three phase slurry reactor.
Alini S, et al.
J. Mol. Catal. A: Chem., 206(1-2), 363-370 (2003)
Pratibha L Gai
Microscopy and microanalysis : the official journal of Microscopy Society of America, Microbeam Analysis Society, Microscopical Society of Canada, 8(1), 21-28 (2004-01-09)
We present the development of in situ wet environmental transmission electron microscopy (wet-ETEM) for direct probing of controlled liquid-catalyst reactions at operating temperatures on the nanoscale. The first nanoscale imaging and electron diffraction of dynamic liquid hydrogenation and polymerization reactions
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