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D79403

双环己烷

Name: 双环己烷
Brand: ALDRICH

99%

别名:

1,1′-双(环己基), BCH, 双环己烷

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关于此项目

线性分子式:

C₆H₁₁C₆H₁₁

化学文摘社编号:

92-51-3

分子量:

166.30

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24894172

EC Number:

202-161-4

Beilstein/REAXYS Number:

1848266

MDL number:

MFCD00003815

Assay:

99%

Form:

liquid

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属性

Quality Level

200

assay

99%

form

liquid

autoignition temp.

473 °F

refractive index

n20/D 1.478 (lit.)

bp

227 °C (lit.)

mp

3-4 °C (lit.)

density

0.864 g/mL at 25 °C (lit.)

SMILES string

C1CCC(CC1)C2CCCCC2

InChI

1S/C12H22/c1-3-7-11(8-4-1)12-9-5-2-6-10-12/h11-12H,1-10H2

InChI key

WVIIMZNLDWSIRH-UHFFFAOYSA-N

Gene Information

human ... CYP1A2(1544), ESR1(2099)

说明

General description

联环己烷，别称双环己烷，是由两个环己烷环经一个碳碳键相连而成的非挥发性液体。

Application

联环己烷可用作反应剂，用于：

以亲核NaN₃为叠氮源，通过Mn催化的氧化叠氮化反应合成1-叠氮-1,1′-联环己烷。
使用氟元素制备1-氟-1,1′-联环己烷。
在脂肪族Friedel-Crafts反应中，与三氯化铝和乙酰氯经C-H活化作用制备基于新型联环己烷的含氧分子砌块。

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pictograms

GHS08,GHS07,GHS09

signalword

Danger

hcodes

H302,H304,H335,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Asp. Tox. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

pcodes

P261 - P264 - P271 - P273 - P301 + P310 - P331

flash_point_f

165.2 °F - closed cup

flash_point_c

74 °C - closed cup

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

0000508760

0000491830

0000471096

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Manganese-Catalyzed Oxidative Azidation of C(sp3)-H Bonds under Electrophotocatalytic Conditions.

Linbin Niu et al.

Journal of the American Chemical Society, 142(41), 17693-17702 (2020-09-18)

The selective installation of azide groups into C(sp3)-H bonds is a priority research topic in organic synthesis, particularly in pharmaceutical discovery and late-stage diversification. Herein, we demonstrate a generalized manganese-catalyzed oxidative azidation methodology of C(sp3)-H bonds using nucleophilic NaN3 as

Understanding the contamination of food with mineral oil: the need for a confirmatory analytical and procedural approach.

Lionel W Spack et al.

Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 34(6), 1052-1071 (2017-03-28)

The contamination of food by mineral oil hydrocarbons (MOHs) found in packaging is a long-running concern. A main source of MOHs in foods is the migration of mineral oil from recycled board into the packed food products. Consequently, the majority

Aliphatic C-H activation with aluminium trichloride-acetyl chloride: expanding the scope of the Baddeley reaction for the functionalisation of saturated hydrocarbons.

Catherine L Lyall et al.

Organic & biomolecular chemistry, 11(9), 1468-1475 (2012-12-25)

The functionalisation of decalin by means of an "aliphatic Friedel-Crafts" reaction was reported over fifty years ago by Baddeley et al. This protocol is of current relevance in the context of C-H activation and here we demonstrate its applicability to

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全球贸易项目编号

货号	GTIN
379387-5G	04061831837063
379387-25G	04061831837056
1006290010	04022536008493
1006290100	04022536008509
D79403-100G	04061833589045
D79403-5G	04061833589069
D79403-25G	04061833589052