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经验公式(希尔记法):
C5H10O3
化学文摘社编号:
分子量:
118.13
UNSPSC Code:
12352108
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-694-1
Beilstein/REAXYS Number:
1720839
MDL number:
产品名称
(-)-L-乳酸乙酯, 98%
InChI key
LZCLXQDLBQLTDK-BYPYZUCNSA-N
InChI
1S/C5H10O3/c1-3-8-5(7)4(2)6/h4,6H,3H2,1-2H3/t4-/m0/s1
SMILES string
C[C@H](O)C(OCC)=O
vapor density
4.1 (vs air)
vapor pressure
2 mmHg ( 20 °C)
5 mmHg ( 30 °C)
assay
98%
form
liquid
optical activity
[α]14/D −10°, neat
autoignition temp.
752 °F
expl. lim.
1.5 %, 100 °F
Quality Level
greener alternative product characteristics
Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
refractive index
n20/D 1.4130 (lit.)
pH
4 (20 °C, 50 g/L)
bp
154 °C (lit.)
mp
−26 °C (lit.)
density
1.034 g/mL at 20 °C (lit.)
1.042 g/mL at 25 °C
greener alternative category
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Application
(−)-L-乳酸乙酯可用于制备:
- (R)-(+)-2-甲基环氧乙烷。
- (S)-2-((叔丁基二甲基硅基)氧基)丙醛,一种用于合成maltepolide的关键中间体。
General description
乳酸乙酯是用于有机合成的绿色环保溶剂。它通常用于多组分反应、环加成反应、不对称诱导、光化学合成和无配体偶联反应等有机反应。
Features and Benefits
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is a safer and more sustainable alternative to ethyl acetate and acetone. It is an ester of natural L-lactic acid, which is produced by fermentation of sugar and thus aligns with "Safer Solvents and Auxiliaries" and "Use of Renewable Feedstocks". Click here for more information.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
128.8 °F - closed cup
flash_point_c
53.8 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
A facile approach for the synthesis of C13-C24 fragments of maltepolides A, C and D
Rao, P Sankara and Srihari, P
Organic & Biomolecular Chemistry, 14(40), 9629-9638 (2016)
Ethyl lactate as a tunable solvent for the synthesis of aryl aldimines
Bennett J, et al.
Green Chemistry, 11(2), 166-168 (2009)
Ethyl lactate as a green solvent: a promising bio-compatible media for organic synthesis
Paul S, et al.
Current Green Chemistry, 3(1), 111-118 (2016)
Shuke Xiao et al.
eLife, 8 (2019-10-28)
Odorant binding proteins (Obps) are expressed at extremely high levels in the antennae of insects, and have long been believed essential for carrying hydrophobic odorants to odor receptors. Previously we found that when one functional type of olfactory sensillum in
Stereocontrolled total synthesis of the macrocyclic lactone (-)-aspicilin.
Waanders PP, et al.
Tetrahedron Letters, 28(21), 2409-2412 (1987)
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