E43101
草酰氯乙酯
98%
别名:
草酰氯单乙酯, 乙基乙二酰氯酯, 乙基草酰氯, 草酸单乙酯酰氯
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关于此项目
线性分子式:
ClCOCOOCH2CH3
化学文摘社编号:
分子量:
136.53
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
225-285-0
Beilstein/REAXYS Number:
506725
MDL number:
产品名称
草酰氯乙酯, 98%
InChI key
OWZFULPEVHKEKS-UHFFFAOYSA-N
InChI
1S/C4H5ClO3/c1-2-8-4(7)3(5)6/h2H2,1H3
SMILES string
CCOC(=O)C(Cl)=O
assay
98%
form
liquid
reaction suitability
reagent type: oxidant
refractive index
n20/D 1.416 (lit.)
bp
135 °C (lit.)
density
1.222 g/mL at 25 °C (lit.)
Quality Level
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Application
氯氧乙酸乙酯可用于合成：
- α-酮酯。
- 官能化3-吡咯啉-2-酮。
- 取代芳基乙醛酸（通过Friedel-Crafts酰化反应）。
- 取代9,10-菲醌。
- 喹喔啉酮衍生物。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
105.8 °F - closed cup
flash_point_c
41 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
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A one-pot synthesis of functionalised 3-pyrolin-2-ones by a four-component reaction between triphenylphosphine, primary amines, dimethyl acetylenedicarboxylate and ethyl chlorooxoacetate.
Anary-Abbasinejad M, et al.
J. Chem. Res. (M), 2007(10), 574-574 (2007)
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Yoshikawa N, et al.
Organic Letters, 9(21), 4103-4106 (2007)
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