F1506
9-芴酮
98%
别名:
9H-芴-9-酮, 芴-9-酮（8CI）
质量水平
方案
98%
沸点
342 °C (lit.)
mp
80-83 °C (lit.)
SMILES字符串
O=C1c2ccccc2-c3ccccc13
InChI
1S/C13H8O/c14-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)13/h1-8H
InChI key
YLQWCDOCJODRMT-UHFFFAOYSA-N
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应用
9-芴酮已被广泛用作合成各种有机电子材料的前体。一些一般的例子是：
- 蓝色和绿色磷光有机发光二极管（PHOLEDs）的主体的合成。
- 芴基分子马达的合成。
- 开壳 Chichibabin 碳氢化合物作为潜在的有机自旋电子材料的合成。
- 通过 1，2-二（1-萘基）乙烷的光敏化作用，它也可以作为一种敏化剂来形成二萘品苯。
警示用语：
Warning
危险声明
危险分类
Aquatic Chronic 2 - Eye Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
325.4 °F
闪点(°C)
163 °C
个人防护装备
Eyeshields, Gloves, type N95 (US)
Novel carbazole/fluorene hybrids: Host materials for blue phosphorescent OLEDs.
Shih P I, et al.
Organic Letters, 8(13), 2799-2802 (2006)
Facile synthesis of picene from 1, 2-di (1-naphthyl) ethane by 9-fluorenone-sensitized photolysis.
Okamoto H, et al.
Organic Letters, 13(10), 2758-2761 (2011)
Stable Tetrabenzo-Chichibabin?s hydrocarbons: tunable ground state and unusual transition between their closed-shell and open-shell resonance forms.
Zeng Z, et al.
Journal of the American Chemical Society, 134(35), 14513-14525 (2012)
Yufang Liu et al.
Journal of computational chemistry, 30(16), 2723-2727 (2009-04-29)
The geometric structures and infrared (IR) spectra in the electronically excited state of a novel doubly hydrogen-bonded complex formed by fluorenone and alcohols, which has been observed by IR spectra in experimental study, are investigated by the time-dependent density functional
Jian Zhao et al.
Journal of the American Chemical Society, 129(16), 5288-5295 (2007-04-03)
Biologically interesting fluoren-9-one and xanthen-9-one derivatives have been prepared by a novel aryl to imidoyl palladium migration, followed by intramolecular arylation. The fluoren-9-one synthesis appears to involve both a palladium migration mechanism and a C-H activation process proceeding through an
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