F1506
9-芴酮
98%
别名:
9H-芴-9-酮, 芴-9-酮(8CI)
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关于此项目
经验公式(希尔记法):
C13H8O
化学文摘社编号:
分子量:
180.20
Beilstein:
1636531
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
98%
沸点
342 °C (lit.)
mp
80-83 °C (lit.)
SMILES字符串
O=C1c2ccccc2-c3ccccc13
InChI
1S/C13H8O/c14-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)13/h1-8H
InChI key
YLQWCDOCJODRMT-UHFFFAOYSA-N
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应用
9-芴酮已被广泛用作合成各种有机电子材料的前体。一些一般的例子是:
- 蓝色和绿色磷光有机发光二极管(PHOLEDs)的主体的合成。
- 芴基分子马达的合成。
- 开壳 Chichibabin 碳氢化合物作为潜在的有机自旋电子材料的合成。
- 通过 1,2-二(1-萘基)乙烷的光敏化作用,它也可以作为一种敏化剂来形成二萘品苯。
警示用语:
Warning
危险声明
危险分类
Aquatic Chronic 2 - Eye Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
325.4 °F
闪点(°C)
163 °C
个人防护装备
Eyeshields, Gloves, type N95 (US)
Jian Zhao et al.
Journal of the American Chemical Society, 129(16), 5288-5295 (2007-04-03)
Biologically interesting fluoren-9-one and xanthen-9-one derivatives have been prepared by a novel aryl to imidoyl palladium migration, followed by intramolecular arylation. The fluoren-9-one synthesis appears to involve both a palladium migration mechanism and a C-H activation process proceeding through an
Harmonizing triplet level and ambipolar characteristics of wide-gap phosphine oxide hosts toward highly efficient and low driving voltage blue and green PHOLEDs: an effective strategy based on spiro-systems.
Zhao J, et al. 
Chemistry of Materials, 23(24), 5331-5339 (2011)
Tuning the rotation rate of light-driven molecular motors.
Bauer J, et al. 
The Journal of Organic Chemistry, 79(10), 4446-4455 (2014)
T Atsumi et al.
Journal of oral rehabilitation, 31(12), 1155-1164 (2004-11-17)
Camphorquinone (CQ) is widely used as a photo-initiator in dental materials; however, its cytotoxicity against human pulp fibroblasts (HPF) and particularly the effects of 2-dimethylaminoethyl methacrylate (DMA), a reducing agent and visible light (VL) irradiation on it remain unknown. So
Novel carbazole/fluorene hybrids: Host materials for blue phosphorescent OLEDs.
Shih P I, et al. 
Organic Letters, 8(13), 2799-2802 (2006)
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