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经验公式(希尔记法):
C6H5I
化学文摘社编号:
分子量:
204.01
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-719-6
Beilstein/REAXYS Number:
1446140
MDL number:
产品名称
碘苯, 98%
InChI key
SNHMUERNLJLMHN-UHFFFAOYSA-N
InChI
1S/C6H5I/c7-6-4-2-1-3-5-6/h1-5H
SMILES string
Ic1ccccc1
assay
98%
refractive index
n20/D 1.62 (lit.)
bp
188 °C (lit.)
mp
−29 °C (lit.)
density
1.823 g/mL at 25 °C (lit.)
Quality Level
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Application
碘苯可用于各种C-C偶联反应。它可用于制备二氯化碘苯,可用作氧化剂将醇氧化成羰基化合物,其也可作为氯化剂。
General description
碘代苯,也称苯基碘,是各种交叉偶联反应中的常用芳基化剂。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
170.6 °F - closed cup
flash_point_c
77 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Zhao, Xue-Fei and Zhang, Chi
Synthesis, 2007(04), 551-557 (2007)
Catalysis by gold (I) and gold (III): a parallelism between homo-and heterogeneous catalysts for copper-free Sonogashira cross-coupling reactions.
Gonzalez-Arellano, Camino et al.
Angewandte Chemie (International Edition in English), 46(9), 1536-1538 (2007)
Heck reactions of iodobenzene and methyl acrylate with conventional supported palladium catalysts in the presence of organic and/and inorganic bases without ligands.
Zhao, Fengyu et al.
Chemistry?A European Journal , 6(5), 843-848 (2000)
Ring-Opening 1, 3-Dichlorination of Donor-Acceptor Cyclopropanes by Iodobenzene Dichloride.
Garve, Lennart KB et al.
Organic Letters, 16(21), 5804-5807 (2014)
商品
Our strategy is to synthesize mesoporous carbonaceous materials (“Starbons”) using mesoporous expanded starch as the precursor without the need for a templating agent.
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