M072000
2-氰乙基N,N-二异丙基氯亚磷酰胺
别名:
氯代(二异丙基氨基)-β-氰基乙氧基膦
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关于此项目
线性分子式:
[(CH3)2CH]2NP(Cl)OCH2CH2CN
化学文摘社编号:
分子量:
236.68
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3588525
InChI key
QWTBDIBOOIAZEF-UHFFFAOYSA-N
SMILES string
CC(C)N(C(C)C)P(Cl)OCCC#N
InChI
1S/C9H18ClN2OP/c1-8(2)12(9(3)4)14(10)13-7-5-6-11/h8-9H,5,7H2,1-4H3
type
for DNA synthesis
product line
Proligo Reagents
assay
≥97.0% (31P-NMR)
form
liquid
color
clear to very slightly hazy colorless
density
1.061 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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General description
2-氰乙基N,N-二异丙基氯代亚磷酰胺是一种用于DNA合成的一氯化磷酸化试剂。
signalword
Danger
hcodes
Hazard Classifications
Pyr. Liq. 1 - Skin Corr. 1B
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
Abdelaziz Al Ouahabi et al.
Journal of the American Chemical Society, 137(16), 5629-5635 (2015-04-09)
Sequence-defined non-natural polyphosphates were prepared using iterative phosphoramidite protocols on a polystyrene solid support. Three monomers were used in this work: 2-cyanoethyl (3-dimethoxytrityloxy-propyl) diisopropylphosphoramidite (0), 2-cyanoethyl (3-dimethoxytrityloxy-2,2-dimethyl-propyl) diisopropylphosphoramidite (1), and 2-cyanoethyl (3-dimethoxytrityloxy-2,2-dipropargyl-propyl) diisopropylphosphoramidite (1'). Phosphoramidite coupling steps allowed rapid synthesis
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