M2876
DL-α-甲氧基苯乙酸
crystalline
别名:
O-甲基-DL-扁桃酸, MOPA
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关于此项目
线性分子式:
C6H5CH(OCH3)COOH
化学文摘社编号:
分子量:
166.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
230-300-9
MDL number:
Beilstein/REAXYS Number:
2209197
Assay:
≥99.0%
Form:
crystalline
assay
≥99.0%
Quality Level
form
crystalline
bp
165 °C ((lit.)), 165 °C/18 mmHg (lit.)
mp
69-71 °C (lit.), 69-71 °C
SMILES string
COC(C(O)=O)c1ccccc1
InChI
[1S/C9H10O3/c1-12-8(9(10)11)7-5-3-2-4-6-7/h2-6,8H,1H3,(H,10,11)], 1S/C9H10O3/c1-12-8(9(10)11)7-5-3-2-4-6-7/h2-6,8H,1H3,(H,10,11)
InChI key
[DIWVBIXQCNRCFE-UHFFFAOYSA-N], DIWVBIXQCNRCFE-UHFFFAOYSA-N
General description
(±)-α-甲氧基苯乙酸，又称MOPA，常用作拆分试剂以及各种有机合成反应原料。
Application
(±)-α-甲氧基苯乙酸可用作合成以下物质的反应物：
- N
- -(环己基甲基)-2-甲氧基-2-苯基乙胺，通过在EDCI/HOBt/Et3N环境下与环己基甲基胺反应。
- 4-(甲氧基苯基甲基)-2-甲基吡啶，通过在光催化剂环境下与2-甲基-4-吡啶碳腈发生脱羧芳基化反应。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
Yiyang Chen et al.
Organic letters, 21(7), 2130-2133 (2019-03-13)
1-(4-(9 H-Carbazol-9-yl)phenyl)-3-amino-9 H-fluorene-2,4-dicarbonitrile as a new photocatalyst for the decarboxylative cross-coupling reaction of α-amino acids or α-oxy carboxylic acids with arylnitriles is described. This light-driven reaction enables a variety of benzylic amines and ethers to be prepared from readily available
Shoko Yamazaki et al.
The Journal of organic chemistry, 82(13), 6748-6763 (2017-06-13)
Catalytic cyclization of amides of ethenetricarboxylate bearing ether and acetal groups has been examined. The reaction of the amides bearing cyclic ether and acetal groups in the presence of Lewis acid such as Sc(OTf)3 gave spirocyclic piperidine derivatives as major
Bin Chang et al.
Journal of clinical microbiology, 53(10), 3318-3324 (2015-08-14)
Streptococcus pneumoniae colonizes the nasopharyngeal mucus in healthy people and causes otitis media, pneumonia, bacteremia, and meningitis. In this study, we analyzed an S. pneumoniae strain that caused 7 repeated pneumonia episodes in an 80-month-old patient with cerebral palsy during
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| M2876-5G | 04061835282357 |
| M2876-10G | 04061835282333 |
| M2876-25G | 04061835282340 |