M46055
3-亚甲基-2-降冰片酮
97%
别名:
3-methylene-bicyclo[2,2,1]heptan-2-one
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关于此项目
经验公式（希尔记法）:
C8H10O
化学文摘社编号:
分子量:
122.16
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
227-009-4
MDL number:
Assay:
97%
assay
97%
refractive index
n
bp
69-71 °C/11 mmHg (lit.)
density
0.997 g/mL at 25 °C (lit.)
SMILES string
C=C1[C@@H]2CC[C@@H](C2)C1=O
InChI
1S/C8H10O/c1-5-6-2-3-7(4-6)8(5)9/h6-7H,1-4H2/t6-,7+/m1/s1
InChI key
FNOOZJAPZFHNCW-RQJHMYQMSA-N
Application
3-Methylene-2-norbornanone can be used as a reactant to prepare:
- 3-(2-(4-methoxyphenyl)-2-oxoethyl)bicyclo[2.2.1]heptan-2-one by reacting with 4-anisaldehyde in the presence of tetrabutylammonium decatungstate (TBADT) photocatalyst.
- 2-Aryl-3-methylene-endo-norbornanols by treating with corresponding aryl lithium reagents.
