M46705
N-甲基甲酰胺
99%
别名:
甲基甲酰胺
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关于此项目
线性分子式:
HCONHCH3
化学文摘社编号:
分子量:
59.07
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
204-624-6
Beilstein/REAXYS Number:
1098352
MDL number:
产品名称
N-甲基甲酰胺, 99%
InChI key
ATHHXGZTWNVVOU-UHFFFAOYSA-N
InChI
1S/C2H5NO/c1-3-2-4/h2H,1H3,(H,3,4)
SMILES string
[H]C(=O)NC
assay
99%
form
liquid
refractive index
n20/D 1.432 (lit.)
bp
198-199 °C (lit.)
mp
−4 °C (lit.)
density
1.011 g/mL at 25 °C (lit.)
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Legal Information
DuPont 产品
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Repr. 1B
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 1
flash_point_f
231.8 °F - closed cup
flash_point_c
111 °C - closed cup
Jolanta Swiergiel et al.
The journal of physical chemistry. B, 113(43), 14225-14228 (2009-10-07)
Impedance spectroscopy was used for studies of the frequency dependence of the electric conductivity of two highly conducting liquid amides: N-methylformamide (NMF), strongly self-associated via the hydrogen bonds C=O...N-H, and N,N-dimethylformamide (DMF), which is not able to self-organize by hydrogen
Jeppe S Spicker et al.
Toxicological sciences : an official journal of the Society of Toxicology, 102(2), 444-454 (2008-01-08)
A large number of databases are currently being implemented within toxicology aiming to integrate diverse biological data, such as clinical chemistry, expression, and other types of data. However, for these endeavors to be successful, tools for integration, visualization, and interpretation
Edward M Kosower et al.
The journal of physical chemistry. B, 113(16), 5622-5632 (2009-03-31)
N-methylformamide (NMF), the simplest model for peptides, exhibits hyperplectic (both simple and complex) behavior as revealed by thin film infrared spectroscopy on planar AgX [AgCl:AgBr] fiber. IR spectra (0.1 s scans) of 10 microg NMF/dichloromethane(DCM) under N(2) flow first show
Walther Caminati et al.
Physical chemistry chemical physics : PCCP, 12(35), 10230-10234 (2010-07-27)
We investigated the Fourier transform microwave spectra of the hydrated forms of N-methylformamide (NMF) in a supersonic expansion and assigned the rotational spectra of two mono-hydrated species. The conformation of each molecular complex was reliably determined on the basis of
Rachel Crespo-Otero et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 14(4), 827-836 (2012-10-04)
The photochemistry of N-methylformamide (MF) is elucidated by investigating its photodissociation products generated by UV irradiation (248 nm) in an argon matrix (10 K). We find that, starting from trans-MF, prolonged irradiation produces cis-MF, CH3NH2 and CO fragments as major
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