M79204
N -甲基吡咯烷
97%
别名:
1-Methylpyrrolidine, N-Methylpyrrolidine, N-Methyltetrahydropyrrole
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关于此项目
经验公式（希尔记法）:
C5H11N
化学文摘社编号:
分子量:
85.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-438-5
Beilstein/REAXYS Number:
102445
MDL number:
产品名称
N -甲基吡咯烷, 97%
InChI
1S/C5H11N/c1-6-4-2-3-5-6/h2-5H2,1H3
InChI key
AVFZOVWCLRSYKC-UHFFFAOYSA-N
SMILES string
CN1CCCC1
assay
97%
form
liquid
bp
80-81 °C (lit.)
density
0.819 g/mL at 25 °C (lit.)
Quality Level
Application
N-甲基吡咯烷可用作制备以下成分的起始材料：
N-甲基吡咯烷-硼氢化锌(ZBHNMP)——这是一种用于还原醛，酮，酰氯和酯的还原剂。ZBHNMP还用于将醛和酮还原胺化为相应的胺。
N-烷基-N-甲基-吡咯烷鎓双（三氟甲磺酰基）亚胺离子液体。
N-甲基吡咯烷-2-酮氢三溴化物可用作烯烃的叠氮化催化剂。
N-甲基吡咯烷-硼氢化锌(ZBHNMP)——这是一种用于还原醛，酮，酰氯和酯的还原剂。ZBHNMP还用于将醛和酮还原胺化为相应的胺。
N-烷基-N-甲基-吡咯烷鎓双（三氟甲磺酰基）亚胺离子液体。
N-甲基吡咯烷-2-酮氢三溴化物可用作烯烃的叠氮化催化剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Flam. Liq. 2 - Skin Corr. 1A
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-0.4 °F - closed cup
flash_point_c
-18 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Reductive amination of aldehydes and ketones to their corresponding amines with N-methylpyrrolidine zinc borohydride
Alinezhad H, et al.
Tetrahedron Letters, 50(6), 659-661 (2009)
N-methylpyrrolidine-2-one hydrotribromide: An efficient and new catalyst for the aziridination of alkenes using Chloramine-T under solvent free conditions
Jain SL, et al.
J. Mol. Catal. A: Chem., 256(1-2), 16-20 (2006)
Effect of the alkyl group on the synthesis and the electrochemical properties of N-alkyl-N-methyl-pyrrolidinium bis (trifluoromethanesulfonyl) imide ionic liquids
Appetecchi GB, et al.
Electrochimica Acta, 54(4), 1325-1332 (2009)
N-Methylpyrrolidine-zinc borohydride: As a new stable and efficient reducing agent in organic synthesis
Tajbakhsh M, et al.
Synthetic Communications, 33(2), 229-236 (2003)
Danah Al-Masri et al.
Physical chemistry chemical physics : PCCP, 22(32), 18102-18113 (2020-08-08)
Ionic liquids and plastic crystals based on pyrrolidinium cations are recognised for their advantageous properties such as high conductivity, low viscosity, and good electrochemical and thermal stability. The pyrrolidinium ring can be substituted with symmetric or asymmetric alkyl chain substituents
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