M79204
N -甲基吡咯烷
97%
别名:
1-Methylpyrrolidine, N-Methylpyrrolidine, N-Methyltetrahydropyrrole
质量水平
方案
97%
表单
liquid
沸点
80-81 °C (lit.)
密度
0.819 g/mL at 25 °C (lit.)
SMILES字符串
CN1CCCC1
InChI
1S/C5H11N/c1-6-4-2-3-5-6/h2-5H2,1H3
InChI key
AVFZOVWCLRSYKC-UHFFFAOYSA-N
应用
N-甲基吡咯烷可用作制备以下成分的起始材料：
N-甲基吡咯烷-硼氢化锌(ZBHNMP)——这是一种用于还原醛，酮，酰氯和酯的还原剂。ZBHNMP还用于将醛和酮还原胺化为相应的胺。
N-烷基-N-甲基-吡咯烷鎓双（三氟甲磺酰基）亚胺离子液体。
N-甲基吡咯烷-2-酮氢三溴化物可用作烯烃的叠氮化催化剂。
N-甲基吡咯烷-硼氢化锌(ZBHNMP)——这是一种用于还原醛，酮，酰氯和酯的还原剂。ZBHNMP还用于将醛和酮还原胺化为相应的胺。
N-烷基-N-甲基-吡咯烷鎓双（三氟甲磺酰基）亚胺离子液体。
N-甲基吡咯烷-2-酮氢三溴化物可用作烯烃的叠氮化催化剂。
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Flam. Liq. 2 - Skin Corr. 1A
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
-0.4 °F - closed cup
闪点(°C)
-18 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
N-Methylpyrrolidine-zinc borohydride: As a new stable and efficient reducing agent in organic synthesis
Tajbakhsh M, et al.
Synthetic Communications, 33(2), 229-236 (2003)
N-methylpyrrolidine-2-one hydrotribromide: An efficient and new catalyst for the aziridination of alkenes using Chloramine-T under solvent free conditions
Jain SL, et al.
J. Mol. Catal. A: Chem., 256(1-2), 16-20 (2006)
Reductive amination of aldehydes and ketones to their corresponding amines with N-methylpyrrolidine zinc borohydride
Alinezhad H, et al.
Tetrahedron Letters, 50(6), 659-661 (2009)
Effect of the alkyl group on the synthesis and the electrochemical properties of N-alkyl-N-methyl-pyrrolidinium bis (trifluoromethanesulfonyl) imide ionic liquids
Appetecchi GB, et al.
Electrochimica Acta, 54(4), 1325-1332 (2009)
Inhibition of acetylcholinesterase by caffeine, anabasine, methyl pyrrolidine and their derivatives.
N Karadsheh et al.
Toxicology letters, 55(3), 335-342 (1991-03-01)
The inhibition of acetylcholinesterase (AChE) by caffeine, anabasine, methylpyrrolidine and several derivatives was examined. Most of the compounds had moderate inhibitory activity with I50 values in the range of 87-480 microM. The inhibition of AChE by these compounds has not
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