N109
1-萘甲醛
95%
别名:
α-萘亚甲基, 萘-1-甲醛, α-萘甲醛
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线性分子式:
C10H7CHO
化学文摘社编号:
分子量:
156.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-633-4
Beilstein/REAXYS Number:
386082
MDL number:
产品名称
1-萘甲醛, 95%
InChI
1S/C11H8O/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-8H
InChI key
SQAINHDHICKHLX-UHFFFAOYSA-N
SMILES string
[H]C(=O)c1cccc2ccccc12
vapor density
>1 (vs air)
assay
95%
form
liquid
refractive index
n20/D 1.652 (lit.)
bp
160-161 °C/15 mmHg (lit.)
mp
1-2 °C (lit.)
density
1.15 g/mL at 25 °C (lit.)
Quality Level
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Application
1-萘甲醛可用于合成：
- ( S )-1-α-萘基-1-乙醇
- N -（4-芳基）- N -（α-萘基）胺
- N -芳基- N - [1-（1-萘基）丁-3-烯基]
- 胺萘-1-羧酸甲酯
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
10 - Combustible liquids
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Highly enantioselective addition of dimethylzinc to arylaldehydes catalyzed by (2S)-1-ferrocenyl-methylaziridin-2-yl (diphenyl) methanol.
Wang M, et al.
Tetrahedron Asymmetry, 20(3), 288-292 (2009)
V Krishnakumar et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 69(2), 528-533 (2007-06-08)
The mid and far FTIR and Raman spectra were measured in the liquid state. The fundamental vibrational frequencies and intensity of vibrational bands were evaluated using density functional theory (DFT) and standard B3LYP/6-311+G** basis set combination. The vibrational spectra were
Carl A Busacca et al.
Magnetic resonance in chemistry : MRC, 48(1), 74-79 (2009-10-08)
Three isomeric o-fluoronaphthaldehydes, 9-fluorophenanthrene, and three previously unreported o-fluorophenanthrene aldehydes were analyzed in detail by multiple NMR techniques to provide unambiguous assignment of structures and resonances. The six aldehydes serve as the key starting materials for novel chiral ligands used
NHC catalyzed oxidations of aldehydes to esters: chemoselective acylation of alcohols in presence of amines.
De Sarkar S, et al.
Journal of the American Chemical Society, 132(4), 1190-1191 (2010)
Magdalena Florek-Luszczki et al.
Epilepsy research, 108(10), 1728-1733 (2014-12-03)
The influence of WIN 55,212-2 mesylate (WIN) on the anticonvulsant activity and acute neurotoxic potential of clobazam (CLB) and lacosamide (LCM) was studied in the maximal electroshock-induced seizure (MES) model and chimney test in mice. indicate that WIN administered intraperitoneally
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